In order to study the high and low temperature properties, and fatigue properties, of silica fume/SBS (Styrene-Butadiene-Styrene) compound modified asphalt (SFSCMA), dynamic shear rheometer (DSR) and bending beam rheometer (BBR) are used to study matrix asphalt (MA), silica fume modified asphalt (SFMA) (silica fume (SF) 6%), SBS modified asphalt (SBSMA) (mass ratio of SBS to Matrix asphalt 4%), and silica fume/SBS compound modified asphalt, and the high temperature rheological properties of silica fume/SBS compound modified asphalt with different silica fume additions are also studied. The modification mechanism of SFSCMA was studied by scanning electron microscope (SEM). The investigation results turn out: along with the increase in the content of SF, the high temperature performance of SFSCMA is improved significantly. When the content of SF is 6%, the high temperature performance is the best. When the content of SF is more than 6%, the high temperature property of SFSCMA is lower than that of SBSMA. It is suggested to choose 6% as the content of SF. Compared with MA, SFMA, and SBSMA, SFSCMA has excellent high temperature performance; compared with MA and SFMA, the low temperature performance of SFSCMA is improved, but it is worse than that of SBSMA. Moreover, when the temperature is lower than −30 °C, its low temperature performance is close to that of MA, or even worse than that of MA. After the compound modification of SF and SBSMA, the fatigue properties of the asphalt are improved, and the fatigue performance of SFSCMA is the best among the four kinds of asphalt. There is a cross-linking force in the network structure of SFSCMA, which restrains the flow of the whole system, so that the stability of the compound modified asphalt is significantly improved, which is favorable to the high temperature performance and fatigue resistance of the compound modified asphalt. However, due to its low mobility, it has a negative impact on the low temperature performance of the compound modified asphalt. In addition, according to previous studies, compared with diatomite, it is proven that SF can reach the same level as diatomite in improving the high temperature performance and fatigue performance of asphalt. Therefore, SF can be used as a good choice of asphalt modifier and can achieve the purpose of waste recycling and environmental protection.
Recently, China has started paying more attention to environmental protection, and the efficient utilization of exhaust gases produced by smelting has emerged as a key problem concern. e silica fume collected from the exhaust gases produced by smelting ferrosilicon or industrial silicon was often used as a cement concrete admixture. Using silica fume as an asphalt modifier can make exhaust gases profitable. In this study, silica fume/SBS composite-modified asphalt mortar was prepared to improve the performance of asphalt. e effects of the silica fume content, temperature, and ratio of filler asphalt on the composite-modified asphalt mortar were studied through the cone penetration, softening point, viscosity, dynamic shear rheological (DSR) test, and bending beam rheometer (BBR) test. e thermal stability of composite-modified asphalt was analyzed through the thermal analysis test. e results showed that with the increase of silica fume content and ratio of filler asphalt, the high-temperature performance of asphalt mortar was improved; the content of silica fume had a great influence on the low-temperature performance of asphalt mortar, the optimum silica fume content was 7%; increasing the ratio of filler asphalt reduced the low-temperature cracking resistance of asphalt mortar; the incorporation of silica fume enhanced the initial decomposition temperature, thermal residual rate, temperature in which the weight loss rate reaches the maximum, and the endothermic peak of maximum temperature and improved the properties of asphalt.
In order to explore the influence mechanism of carbon nanotubes on the ultraviolet (UV) aging properties of the SBS-modified asphalt binder, the changes of functional groups in the one-dimensional infrared spectrum and two-dimensional infrared correlation spectrum are studied in this paper. The results show that the UV aging process of the SBS-modified asphalt binder is the process of alkane chain cleavage and reorganization, the formation of oxygen-containing functional groups and decomposition of SBS. The incorporation of carbon nanotubes can reduce the mutual conversion of methyl and methylene functional groups, inhibit the decomposition of butadiene and the destruction of C = C double bonds in SBS. The degradation of SBS during the process of UV aging leads to the change of many functional groups and acceleration of the aging of the SBS-modified asphalt binder. The addition of carbon nanotubes can effectively alleviate the degradation of SBS and the formation of oxygen-containing functional groups at the early stage of UV aging, and reduce the influence of these two changes on other functional groups; thus, improving the anti-aging performance of the SBS-modified asphalt binder.
A real rejuvenator must have the ability to disaggregate oxidized asphaltene nanoclusters. However, few studies pay attention to the topic, and there is a lack of comparison of the disaggregation ability of different rejuvenators. Thus, the disaggregation ability and regeneration mechanism of three bio-rejuvenators (waste cooking oil (WCO), waste wood oil (WWO), and straw liquefied residue oil (SLRO)) on oxidized asphaltene nanoclusters were studied in this paper. Laboratory tests and molecular dynamics (MD) simulation were used to compare the effectiveness of the three bio-rejuvenators and reveal its corresponding mechanism. It is found that these bio-rejuvenators have a softening effect on aged asphalt binder, but not all of them can disaggregate oxidized asphaltene nanoclusters. The introduction of WWO and WCO can effectively disturb the nanoclusters caused by the increase of polar functional groups during the oxidation process. The effect of WWO is more significant, but neither of them can restore the asphaltene dispersion to the virgin asphalt binder. SLRO has an adverse effect on the disaggregation of oxidized asphaltene nanoclusters. WCO, WWO, and SLRO showed different disaggregation mechanisms, including ″pull-out, intercalation, and compression″, respectively. WCO and WWO can increase the activation energy reduced by aging in a short aging time, and SLRO makes the activation energy lower. Such findings can help enterprises screen more reasonable rejuvenators to facilitate the recycling of reclaimed asphalt pavement (RAP) materials and promote the sustainable development of the construction industry.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
hi@scite.ai
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.