In this study, a facile, two‐step dip‐coating approach was reported for the fabrication of the superhydrophobic and superoleophobic cotton fabrics. It was confirmed that the superhydrophobic and superoleophobic composite thin film containing modified‐SiO2 nanoparticles and fluoropolymer had been successfully fabricated on the cotton fabrics surface, the results demonstrated that the treated cotton fabrics showed good performances, such as superhydrophobicity and superoleophobicity, low water and oil absorption ability, self‐cleaning property and good laundering durability, so forth. The above approach can be applied to potentially advance superhydrophobic and superoleophobic fabrics materials for a variety of applications. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 41458.