To investigate the characteristics of oil distribution in porous media systems during a high water cut stage, sandstones with different permeability scales of 53.63 × 10−3 μm2 and 108.11 × 10−3 μm2 were imaged under a resolution of 4.12 μm during a water flooding process using X-ray tomography. Based on the cluster-size distribution of oil segmented from the tomography images and through classification using the shape factor and Euler number, the transformation of the oil distribution pattern in different injection stages was studied for samples with different pore structures. In general, the distribution patterns of an oil cluster continuously change during water injection. Large connected oil clusters break off into smaller segments. The sandstone with a higher permeability (108.11 × 10−3 μm2) shows the larger change in distribution pattern, and the remaining oil is trapped in the pores with a radius of approximately 7–12 μm. Meanwhile, some disconnected clusters merge together and lead to a re-connection during the high water cut period. However, the pore structure becomes compact and complex, the residual nonwetting phase becomes static and is difficult to move; and thus, all distribution patterns coexist during the entire displacement process and mainly distribute in pores with a radius of 8–12 μm. For the pore-scale entrapment characteristics of the oil phase during a high water cut period, different enhance oil recovery (EOR) methods should be considered in sandstones correspondent to each permeability scale.

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Oil–brine interfaces play an important role in oil recovery and oil–brine separation, in which the effects of salinity on interfacial tension (IFT) have been much of debate in the past in experiments and modeling studies owing to complex oil compositions. In this work, we use molecular dynamics (MD) simulations to study the oil–brine interfacial properties by designing seven systems containing different oil compositions (decane with/without polar compounds) and the salinity in brine of up to ∼14 wt %. We carefully investigate the salinity and polar component effects by analyzing IFTs, density profiles, orientation parameters, hydrogen bond densities, and charge density profiles. The results indicate that O-bearing compounds (phenol and decanoic acid) can significantly reduce the oil–brine IFT and exhibit the highest Gibbs surface excess relative to water, while the others, including N-bearing compounds (pyridine and quinoline) and S-bearing compounds (thiophene and benzothiophene), only slightly decrease the oil–brine IFTs and show a relatively small Gibbs surface excess. Increasing salinity can slightly increase the oil–brine IFT except in the system containing phenol, which shows a decrease. Phenol and decanoic acid incline to be perpendicular to the interface and generate numerous hydrogen bonds with water in the interfacial region, while others prefer to be parallel to the interface with much fewer hydrogen bonds with water. On the other hand, salinity has an insignificant effect on the orientation of polar molecules and hydrogen bond density in the interfacial region. The charges at the interfaces on the brine and oil sides are negative and positive, respectively, and the polar compounds disturb the arrangement of water molecules in the interfacial regions, while the addition of salt ions result in the higher peak values of charges in terms of water and system. Our study should provide new insights into the oil–brine interfacial issues and clarify some unsettled disputes.

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CO2 huff-n-puff has been proven to be the most effective enhanced oil recovery (EOR) method in shale oil reservoirs. The injected CO2 will replenish reservoir energy and penetrate the reservoir matrix to extract oil. However, the CO2 sweep volume during the huff-n-puff process has not been accurately evaluated by existing studies. In this paper, the CO2 sweep volume was investigated through experimental and numerical simulation methods. In the experimental study, the CO2 sweep areas were depicted by X-ray computed tomography scan technology. The results indicated that the ratio of the CO2 sweep area was 78.63% in the seventh huff-n-puff cycle, leading to a total oil recovery of 56.80%. The numerical simulation considered the mechanisms of molecular diffusion and nanopore confinement. The results showed that in the first huff-n-puff cycle, the gas sweep volume percentage was 9.47% after 100 days of huff period. In the gas swept volume, oil viscosity was reduced by 25.9% to 68.2%. After three cycles of CO2 injection, the oil recovery manifested a 1.5% increase compared to the case without huff-n-puff. The contributions of different parameters on gas sweep volume and cumulative oil recovery were investigated. The results illustrated that the nanopore confinement effect and molecular diffusion had significant impacts on the gas sweep volume and cumulative oil recovery. Higher injection pressure, longer huff time, and more huff-n-puff cycles lead to larger gas sweep volume, as well as cumulative oil recovery. A suitable primary depletion period and a huff-n-puff schedule should be determined based on the requirements of field production. The investigations in this study provide insights into better understanding of the EOR mechanisms and optimizing the design of CO2 huff-n-puff operations in shale oil reservoirs.

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