A three-dimensional nanoporous NiO film was fabricated using a two-step process through an electrochemical route. The as-prepared NiO film exhibited a highly nanoporous structure and high surface area (264 m 2 g À1 ). The textural characterization of the film and its electrochemical performance as an electrochemical electrode were investigated. The electrode showed a high specific capacitance (1776 F g À1 ), power density (89 Wh kg À1 ), and energy density (16.5 kW kg À1 ). In addition, the electrode exhibited high and stable specific capacitance retention after a long cycle test in KOH solution. More importantly, the power density met the power requirements of the Partnership for a New Generation of Vehicles (PNGV).

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Popular and readily available alkenes and alkynes are good substrates for the preparation of functionalized molecules through radical and/or ionic addition reactions. Difunctionalization is a topic of current interest due to its high efficiency, substrate versatility, and operational simplicity. Presented in this article are radical addition followed by oxidation and nucleophilic addition reactions for difunctionalization of alkenes or alkynes. The difunctionalization could be accomplished through 1,2-addition (vicinal) and 1,n-addition (distal or remote) if H-atom or group-transfer is involved in the reaction process. A wide range of moieties, such as alkyl (R), perfluoroalkyl (Rf), aryl (Ar), hydroxy (OH), alkoxy (OR), acetatic (O2CR), halogenic (X), amino (NR2), azido (N3), cyano (CN), as well as sulfur- and phosphorous-containing groups can be incorporated through the difunctionalization reactions. Radicals generated from peroxides or single electron transfer (SET) agents, under photoredox or electrochemical reactions are employed for the reactions.