Highly stretchable graphene-nanocellulose composite nanopaper is fabricated for strain-sensor applications. Three-dimensional macroporous nanopaper from crumpled graphene and nanocellulose is embedded in elastomer matrix to achieve stretchability up to 100%. The stretchable graphene nanopaper is demonstrated for efficient human-motion detection applications.
Stretchable and wearable WO3 electrochromic devices on silver nanowire (AgNW) elastic conductors are reported. The stretchable devices are mechanically robust and can be stretched, twisted, folded, and crumpled without performance failure. Fast coloration (1 s) and bleaching (4 s) time and good cyclic stability (81% retention after 100 cycles) were achieved at relaxed state. Proper functioning at stretched state (50% strain) was also demonstrated. The electrochromic devices were successfully implanted onto textile substrates for potential wearable applications. As most existing electrochromic devices are based on rigid technologies, the innovative devices in their soft form hold the promise for next-generation electronics such as stretchable, wearable, and implantable display applications.
Fabrication of intrinsically stretchable nanowire photodetectors based on fully embedded structures is reported. A lithographic filtration method is used to integrate different functional layers into the photodetectors, which exhibit excellent stretchability up to 100%. The fully embedded structure enables excellent stability against repeated stretching, mechanical scratching, and adhesive forces.
Stretchable devices with good transparency offer exciting new applications over the existing technologies, but remarkable difficulties remain in the fabrication of transparent and stretchable devices. In this paper, we report an effective method to fabricate transparent elastic photodetectors which combines the merits of the transparent polydimethylsiloxane (PDMS) polymer with its stretchability and the Zn₂SnO₄ nanowire (NW) with its photodetection functionality. Zonyl fluorosurfactant is found to be critical which improves the bonding between the functional NWs and the PDMS matrix, thus enabling the high efficient transfer of NW structures into PDMS. Highly conductive and thin percolating AgNW films were successfully embedded into PDMS mixed with ∼11% Zonyl which are otherwise not achievable with pure PDMS. Transparent and stretchable photodetectors were fabricated with the developed method. The photocurrent was found to be reciprocal to the square of the channel length, Iph∼ 1/l(2). The chemically bonded sensing materials in the PDMS matrix allow more NW exposure to air. This lead to a fast switching operation of the photodetectors with a response time below 0.8 s and a reset time around 3 s, which is significantly improved compared to reported stretchable NW photodetectors fully embedded in the polymer matrix.
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