Two soluble poly(phenyltriazolylcarboxylate)s (PPTCs) with high molecular weights (M up to 26 800) are synthesized by the metal-free 1,3-dipolar polycycloadditions of 4,4'-isopropylidenediphenyl diphenylpropiolate (1) and tetraphenylethene-containing diazides (2) in dimethylformamide at 150 °C for 12 h in high yields (up to 93%). The resultant polymers are soluble in common organic solvents and are thermally stable with 5% weight loss temperatures higher than 375 °C. The PPTCs are nonemissive in solutions, but become highly luminescent upon aggregation, showing a phenomenon of aggregation-induced emission. Their aggregates can be used as fluorescent chemosensors for high-sensitivity detection of explosives.

Metal-free polycycloaddition of phenylpropiolates and azide is developed to afford multifunctional triazole-containing polyesters.

The 1,3‐dipolar cycloaddition of activated internal alkynes with azides has been developed into an efficient polymerization reaction for constructing functional linear 1,4,5‐trisubstitued polytriazoles. However, it is rarely employed for the synthesis of hyperbranched polymers. In this work, metal‐free polycycloadditions of tris(3‐phenylpropiolate)s (1) and tetraphenylethene‐containing diazides (2) are performed in dimethylformamide at 100 °C for 7 and 12 h, producing hyperbranched poly(phenyltriazolylcarboxylate)s (hb‐PPTCs) with high molecular weights and satisfactory regioregularities in good yields. The hb‐PPTCs have good solubility in common organic solvents and high thermal stability. They are non‐emissive in solutions, but emit intensively upon aggregation, showing an aggregation‐induced emission effect. Their aggregates can work as fluorescent sensors for explosive detection with high sensitivity. Furthermore, the polymers can be utilized for the fabrication of 2D fluorescent patterns with high resolution by UV irradiation through copper grid masks.

Ferrocene-based polymers have drawn much attention in the past decades due to their unique properties and promising applications. However, the synthesis of hyperbranched polymers is still a great challenge. Here, two ferrocene-based hyperbranched polytriazoles with high molecular weights are facilely prepared by the click polymerization reactions of ferrocene-containing diazides (1) and tris(4-ethynylphenyl)amine (2) using Cu(PPh ) Br as catalyst in dimethylformamide at 60 °C for 5 and 9 h in satisfactory yields of 54.0% and 52.3%. The resulting polytriazoles are soluble in common organic solvents and thermally stable, with 5% weight loss temperatures up to 307 °C. They can be used as precursors to produce nanostructured ceramics with good magnetizability by pyrolysis at elevated temperature.

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