As a new member of the MXene group, 2D Mo C has attracted considerable interest due to its potential application as electrodes for energy storage and catalysis. The large-area synthesis of Mo C film is needed for such applications. Here, the one-step direct synthesis of 2D Mo C-on-graphene film by molten copper-catalyzed chemical vapor deposition (CVD) is reported. High-quality and uniform Mo C film in the centimeter range can be grown on graphene using a Mo-Cu alloy catalyst. Within the vertical heterostructure, graphene acts as a diffusion barrier to the phase-segregated Mo and allows nanometer-thin Mo C to be grown. Graphene-templated growth of Mo C produces well-faceted, large-sized single crystals with low defect density, as confirmed by scanning transmission electron microscopy (STEM) measurements. Due to its more efficient graphene-mediated charge-transfer kinetics, the as-grown Mo C-on-graphene heterostructure shows a much lower onset voltage for hydrogen evolution reactions as compared to Mo C-only electrodes.
Results of the first detailed study of the climate proxy record in the loess-palaeosol sequence at Xining-one of the few palaeoclimate sites in the currently arid western Loess Plateau of China-illustrate the importance of making many types of rockmagnetic measurements other than susceptibility. A multiparameter approach yielded confirmation that here, as elsewhere in the Loess Plateau, the susceptibility enhancement in palaeosols was caused primarily by ultrafine magnetite and maghaemite. Nevertheless, magnetic enhancement was caused not exclusively by changes in relative grain size, but also by variations in concentration and mineralogy of the magnetic fraction.The effects of concentration variations were removed through normalization of susceptibility and anhysteretic remanence with saturation magnetization and saturation remanence, respectively. The resulting signal was ascribed more confidently to variation in magnetic grain size, which in turn was interpreted as a better proxy of pedogenesis than simple susceptibility. Variations in magnetic mineralogy were also determined to constrain interpretations further. The data were then used to discuss climate history at Xining. Finally, results from Xining were compared with other western sites and contrasted with eastern sites.In summary: (1) data is presented from a new Loess Plateau site which also appears to yield a global climate signal; (2) a demonstration is made of a more rock-magnetically robust way to separate concentration, composition and grain-size controls on susceptibility and other magnetic parameters; and (3) models are provided for inter-regional comparisons of palaeoclimate proxy records.
Enhancing the energy stored and power delivered by layered materials relies strongly on improved understanding of the intricate interplay of electrolyte ions, solvents, and electrode interactions as well as the...
Developing strategies for atomic-scale controlled synthesis of new two-dimensional (2D) functional materials will directly impact their applications. Here, using in situ aberration-corrected scanning transmission electron microscopy, we obtain direct insight into the homoepitaxial Frank–van der Merwe atomic layer growth mechanism of TiC single adlayers synthesized on surfaces of Ti3C2 MXene substrates with the substrate being the source material. Activated by thermal exposure and electron-beam irradiation, hexagonal TiC single adlayers form on defunctionalized surfaces of Ti3C2 MXene at temperatures above 500 °C, generating new 2D materials Ti4C3 and Ti5C4. The growth mechanism for a single TiC adlayer and the energies that govern atom migration and diffusion are elucidated by comprehensive density functional theory and force-bias Monte Carlo/molecular dynamics simulations. This work could lead to the development of bottom-up synthesis methods using substrates terminated with similar hexagonal-metal surfaces, for controllable synthesis of larger-scale and higher quality single-layer transition metal carbides.
MXenes
(two-dimensional transition-metal carbides and nitrides) are promising
materials for capacitive energy storage due to the large chemical
space of existing and potential compositions, but only a few of them
have been experimentally explored. In this work, we computationally
screen a series of MXene electrodes (M
n+1X
n
T
x
: M =
Sc, Ti, V, Zr, Nb, Mo; X = C, N; T = O, OH; n = 1–3)
to simulate their pseudocapacitive performance in the aqueous H2SO4 electrolyte. We find that nitride MXenes exhibit
better pseudocapacitive performance than carbide MXenes. Especially,
Ti2NT
x
is predicted to have
a high gravimetric capacitance over a wide voltage window, whereas
Zr
n+1N
n
T
x
MXenes are predicted to possess the best areal
capacitive performance. Evaluating the descriptors for the capacitance
trends, we find that more positive hydrogen adsorption free energy
(weak binding to H) and smaller change of the potential at the point
of zero charge after H binding lead to higher capacitance. Our work
provides helpful guidance to selectively develop high-performance
MXene pseudocapacitors and to further screen MXene electrodes.
MXenes (M
n+1X
n
, e.g., Ti3C2) are the largest 2D material family developed in recent
years. They exhibit significant potential in the energy sciences,
particularly for energy storage. In this review, we summarize the
progress of the computational work regarding the theoretical design
of new MXene structures and predictions for energy applications including
their fundamental, energy storage, and catalytic properties. We also
outline how high-throughput computation, big data, and machine-learning
techniques can help broaden the MXene family. Finally, we present
some of the major remaining challenges and future research directions
needed to mature this novel materials family.
Novel wide band gaps and magnetism in ordered titanium-vanadium, titanium-chromium, and titanium-manganese carbide and nitride based MXenes are predicted using density functional theory. Based on the recent synthesis of Ti centred double transition metal MXenes, we study MXenes with a central Ti layer and different surface early 3d metals, and various terminations, TiM2X2T (M = V, Cr, Mn; X = C, N; T = H, F, O, OH). While previously studied MXenes are strongly metallic, we predict surface metal and termination dependent metal-insulator transitions in the Cr-N and Mn-N series. A uniquely wide band gap over 1 eV is predicted for TiMn2N2F2 using the HSE06 density functional while the unterminated TiMn2N2 remains metallic. The entire TiCr2C2T series is predicted to be semiconducting. Distinct from the more common Ti-C MXenes, not all combinations of metals and terminations are predicted to be stable. Within the examined sets of materials, anti-ferromagnetic orders are generally most favorable. The new MXenes further extend the range of properties accessible in this family of two-dimensional nanomaterials.
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