The appearance of detritus shed from mountain ranges along the northern margin of the Tibetan Plateau heralds the Cenozoic development of high topography. Current estimates of the age of the basal conglomerate in the Qaidam basin place this event in Paleocene-Eocene. Here we present new magnetostratigraphy and mammalian biostratigraphy that refine the onset of basin fill to ∼25.5 Myr and reveal that sediment accumulated continuously until ∼4.8 Myr. Sediment provenance implies a sustained source in the East Kunlun Shan throughout this time period. However, the appearance of detritus from the Qilian Shan at ∼12 Myr suggests emergence of topography north of the Qaidam occurred during the late Miocene. Our results imply that deformation and mountain building significantly post-date Indo-Asian collision and challenge the suggestion that the extent of the plateau has remained constant through time. Rather, our results require expansion of high topography during the past 25 Myr.

The uplift processes of the Qilian Shan (northern Tibetan Plateau) play a central role in our understanding of the dynamics of outward and upward growth of Tibet due to sustained convergence of the Indian and Asian plates. We employ apatite fission track chronology and geological mapping to reveal the time and pattern of the deformation along the Qilian Shan. Our results indicate that the emergence of the Tuolai Shan in the central Qilian Shan occurred at 17-14 Ma, that northern Qilian Shan thrusting began at 10-8 Ma, and that the Laojunmiao anticline formed ca. 3.6 Ma. Together with previous results that show that uplift of the southern Qilian Shan began in the Oligocene, we suggest that the Qilian Shan has undergone progressively northward expansion in the Cenozoic due to significant crustal shortening driven by Qilian Shan thrust fault systems.

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Sedimentary deposits in Tibetan Basins archive the spatial‐temporal patterns of the deformation and surface uplift processes that created the area's high topography during the Cenozoic India‐Asia collision. In this study, new stratigraphic investigation of the Caogou section from the Jiuxi Basin in the northeasternmost part of Tibetan Plateau provides chronologic constraints on the deformation and northward growth of the plateau. Magnetostratigraphic analysis results suggest that the age of the studied ~1000 m thick section spans from ~24.2 Ma to 2.8 Ma. Detailed sedimentology and apatite fission track (AFT) analyses reveal that variations in the clast provenance, lithofacies, sediment accumulation rates, and AFT lag times occurred at ~13.5–10.5 Ma. We interpret these changes as in response to the initial uplift of the North Qilian Shan. In addition, paleomagnetic declination results from the section indicate a clockwise rotation of the Jiuxi Basin before ~13.5 Ma, which was followed by a subsequent counterclockwise rotation during 13.5–9 Ma. This reversal in rotation direction may be directly related to left‐lateral strike‐slip activity along the easternmost segment of the Altyn Tagh Fault. Combined with previous studies, we suggest that movement on the western part of the Altyn Tagh Fault was probably initiated during the Oligocene (>30 Ma) and that fault propagation to its eastern tip occurred during the middle‐late Miocene.

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Magnetostratigraphy of sedimentary rock deposited in the Chaka basin (north-eastern Tibetan Plateau) indicates a late Miocene onset of basin formation and subsequent development of the adjacent Qinghai Nan Shan. Sedimentation in the basin initiated at $11 Ma. In the lower part of the basin ¢ll, a coarsening-upward sequence starting at $9 Ma, as well as rapid sedimentation rates, and northward paleocurrents, are consistent with continued growth of the Ela Shan to the south. In the upper section, several lines of evidence suggest that thrust faulting and topographic development of the Qinghai Nan Shan began at $6.1 Ma. Paleocurrent indicators, preserved in the basin in the proximal footwall of the Qinghai Nan Shan, show a change from northward to southward £ow between 6.5 and 3.8 Ma. At the same location, sediment derived from the Qinghai Nan Shan appears at 6.1 Ma. Finally, the initiation of progressively shallowing dips observed in deformed basin strata and a change to pebbly, £uvial deposits at 6.1 Ma provide a minimum age for the onset of slip on the thrust fault that dips north-east beneath the Qinghai Nan Shan.We interpret a decrease in sediment accumulation rates since $6 Ma to indicate a reduction in Chaka basin accommodation space due to active faulting and folding along the Qinghai Nan Shan and incorporation of the basin into the wedge-top depozone. Declination anomalies indicate the beginning of counter-clockwise rotation since 6.1Ma, which we associate with local deformation, not regional block rotation.The emergence of the Qinghai Nan Shan near the end of the Miocene Epoch partitioned the once contiguous Chaka-Gonghe and Qinghai basin complex. In a regional framework, our study adds to a growing body of evidence that points to widespread initiation and/or reactivation of fault networks during the late Miocene across the northeastern Tibetan Plateau.

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Design and preparation of efficient and economical catalysts for direct hydroxylation of benzene to phenol is an important topic. In this work, a series of metal‐doped graphitic carbon nitride catalyst (Cu‐, Fe‐, V‐, Co‐, and Ni‐g‐C3N4) were successfully synthesized by using urea as the precursor through a facile and efficient method. The catalysts were characterized systematically using N2 adsorption–desorption, FTIR, thermogravimetric analysis, powder X‐ray diffraction, and X‐ray photoelectron spectroscopy techniques. It was found that the vanadium‐doped graphitic carbon nitride catalyst V‐g‐C3N4 was the most efficient catalyst for the direct synthesis of phenol from benzene with hydrogen peroxide as the oxidant and it could be recycled at least 4 times. The influence of reaction conditions such as the solvent, reaction temperature, reaction time, and the amounts of catalyst and hydrogen peroxide were investigated. Under optimized conditions, 18.2 % yield of phenol was obtained with the selectivity to phenol as high as 100 %.