A new design for second near-infrared window (NIR-II) molecular fluorophores based on a shielding unit-donor-acceptor-donor-shielding unit (S-D-A-D-S) structure is reported. With 3,4-ethylenedioxy thiophene as the donor and fluorene as the shielding unit, the best performance fluorophores IR-FE and IR-FEP exhibit an emission quantum yield of 31% in toluene and 2.0% in water, respectively, representing the brightest organic dyes in NIR-II region reported so far.

Organic fluorophores have been widely used for biological imaging in the visible and the first near-infrared windows. However, their application in the second near-infrared window (NIR-II, 1000-1700 nm) is still limited mainly due to low fluorescence quantum yields (QYs). Here, we explore molecular engineering on the donor unit to develop high performance NIR-II fluorophores. The fluorophores are constructed by a shielding unit-donor(s)-acceptor-donor(s)-shielding unit structure. Thiophene is introduced as the second donor connected to the shielding unit, which can increase the conjugation length and red-shift the fluorescence emission. Alkyl thiophene is employed as the first donor connected to the acceptor unit. The bulky and hydrophobic alkyl thiophene donor affords larger distortion of the conjugated backbone and fewer interactions with water molecules compared to other donor units studied before. The molecular fluorophore IR-FTAP with octyl thiophene as the first donor and thiophene as the second donor exhibits fluorescence emission peaked at 1048 nm with a QY of 5.3% in aqueous solutions, one of the highest for molecular NIR-II fluorophore reported so far. Superior temporal and spatial resolutions have been demonstrated with IR-FTAP fluorophore for NIR-II imaging of the blood vessels of a mouse hindlimb.

Intramolecular through‐space charge‐transfer (TSCT) excited states have been exploited for developing thermally activated delayed fluorescence (TADF) emitters, but the tuning of excited state dynamics by conformational engineering remains sparse. Designed here is a series of TSCT emitters with precisely controlled alignment of the donor and acceptor segments. With increasing intramolecular π–π interactions, the radiative decay rate of the lowest singlet excited state (S1) progressively increased together with a suppression of nonradiative decay, leading to significantly enhanced photoluminescence quantum yields of up to 0.99 in doped thin films. A high‐efficiency electroluminescence device, with a maximum external quantum efficiency (EQE) of 23.96 %, was achieved and maintains >20 % at a brightness of 1000 cd m−2. This work sheds light on the importance of conformation control for achieving high‐efficiency intramolecular exciplex emitters.

A wound dressing which can be convenient for real-time monitoring of wounds is particularly attractive and user-friendly. In this study, a nature-originated silk-sericin-based (SS-based) transparent hydrogel scaffold was prepared and evaluated for the visualization of wound care. The scaffold was fabricated from a hybrid interpenetrating-network (IPN) hydrogel composed of SS and methacrylic-anhydride-modified gelatin (GelMA) by 3D printing. The scaffold transformed into a highly transparent hydrogel upon swelling in PBS, and thus, anything underneath could be easily read. The scaffold had a high degree of swelling and presented a regularly macroporous structure with pores around 400 μm × 400 μm, which can help maintain the moist and apinoid environment for wound healing. Meanwhile, the scaffolds were conducive to adhesion and proliferation of L929 cells. A coculture of HaCaT and HSF cells on the scaffold showed centralized proliferation of the two cells in distributed layers, respectively, denoting a promising comfortable environment for re-epithelialization. Moreover, in vivo studies demonstrated that the scaffold showed no excessive inflammatory reaction. In short, this work presented an SS-based transparent hydrogel scaffold with steerable physical properties and excellent biocompatibility through 3D printing, pioneering promising applications in the visualization of wound care and drug delivery.

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Chiral materials with circularly polarized luminescence (CPL) are potentially applicable for 3D displays. In this study, by decorating the pyridinyl‐helicene ligands with ‐CF3 and ‐F groups, the platinahelicene enantiomers featured superior configurational stability, as well as high sublimation yield (>90 %) and clear CPPL properties, with dissymmetry factors (|gPL|) of approximately 3.7×10−3 in solution and about 4.1×10−3 in doped film. The evaporated circularly polarized phosphorescent organic light‐emitting diodes (CP‐PhOLEDs) with two enantiomers as emitters exhibited symmetric CPEL signals with |gEL| of (1.1–1.6)×10−3 and decent device performances, achieving a maximum brightness of 11 590 cd m−2, a maximum external quantum efficiency up to 18.81 %, which are the highest values among the reported devices based on chiral phosphorescent PtII complexes. To suppress the effect of reverse CPEL signal from the cathode reflection, the further implementation of semitransparent aluminum/silver cathode successfully boosts up the |gEL| by over three times to 5.1×10−3.

We have carried out a simulation of QCD using the hybrid-molecular-dynamics algorithm with two flavors of staggered quarks. The spectrum was calculated for 6/g2=5. 6 and dynamical quark masses a m , =0.025 and 0.01. Lattice sizes of l2', 1 2~x 2 4 , and 16' were used to generate the gauge configurations. Hadron propagators were calculated with both staggered and Wilson quarks on doubled or quadrupled lattices. Finite-size effects are visible on the smaller lattices. Some improvement in the p-to-nucleon mass ratio and chiral symmetry is seen as compared to previous calculations, but, as in most lattice calculations, the proton-to-p mass ratio remains larger than in the real world and the proton-h splitting is too small.

Quantum-dot cellular automata (QCA) technology is expected to offer fast computation performance, high density, and low power consumption. Thus, researchers believe that QCA may be an attractive alternative to CMOS for future digital designs. Side channel attacks, such as power analysis attacks, have become a significant threat to the security of CMOS cryptographic circuits. A power analysis attack can reveal the secret key from measurements of the power consumption during the encryption and decryption process. As there is no electric current flow in QCA technology, the power consumption of QCA circuits is extremely low when compared to their CMOS counterparts. Therefore, in this paper an investigation into both the best and worst case scenarios for attackers is carried out to ascertain if QCA circuits are immune to power analysis attack. A QCA design of a submodule of the Serpent cipher is proposed. In comparison to a previous design, the proposed design is more efficient in terms of complexity, area, and latency. By using an upper bound power model, the first power analysis attack of a QCA cryptographic circuit is presented. The simulation results show that even though the power consumption is low, it can still be correlated with the correct key guess, and all possible subkeys applied to the Serpent submodule can be revealed in the best case scenario. Therefore, in theory QCA cryptographic circuits would be vulnerable to power analysis attack. However, the security of practical QCA devices can be greatly improved by applying a smoother clock. Moreover, in the worst case scenario, the design of logically reversible QCA circuits with Bennett clocking could be used as a natural countermeasure to power analysis attack. Therefore, it is believed that QCA could be a niche technology in the future for the implementation of security architectures resistant to power analysis attack