Disorder-induced electron localization and metal-insulator transitions (MITs) have been a very active research field starting from the seminal paper by Anderson half a century ago. However, pure Anderson insulators are very difficult to identify due to ubiquitous electron-correlation effects. Recently, an MIT has been observed in electrical transport measurements on the crystalline state of phase-change GeSbTe compounds, which appears to be exclusively disorder driven. Subsequent density functional theory simulations have identified vacancy disorder to localize electrons at the Fermi level. Here, we report a direct atomic scale chemical identification experiment on the rocksalt structure obtained upon crystallization of amorphous Ge2Sb2Te5. Our results confirm the two-sublattice structure resolving the distribution of chemical species and demonstrate the existence of atomic disorder on the Ge/Sb/vacancy sublattice. Moreover, we identify a gradual vacancy ordering process upon further annealing. These findings not only provide a structural underpinning of the observed Anderson localization but also have implications for the development of novel multi-level data storage within the crystalline phases.

We discuss several possible experimental signatures of the Bose-Einstein condensation (BEC) transition for an ultracold Bose gas in an inhomogeneous optical lattice. Based on the commonly used time-of-flight imaging technique, we show that the momentum-space density profile in the first Brillouin zone, supplemented by the visibility of interference patterns, provides valuable information about the system. In particular, by crossing the BEC transition temperature, the appearance of a clear bimodal structure sets a qualitative and universal signature of this phase transition. Furthermore, the momentum distribution can also be applied to extract the condensate fraction, which may serve as a promising thermometer in such a system.Comment: 12 pages, 13 figures; Revised version with new figures; Phys. Rev. A 77, 043626 (2008

An equilibrium phase diagram satisfying the Gibbs phase rule is computed for the PbZrO3-PbTiO3 (PZT) system from a low-order Landau expansion in the approximation of the theory of regular solutions. We show that in the equilibrium phase diagram, miscibility gaps replace the morphotropic phase boundary and the paraelectric to ferroelectric transition lines of the “diffusionless” phase diagram. The decomposition occurs by a peritectoid reaction and the miscibility gaps expand significantly with increasing positive values of the atomic exchange interaction parameter. Diffusional processes are estimated to be sufficiently fast to achieve two-phase equilibria at normal rates of cooling used to process PZT materials.

Bundle-like α'-NaV2O5 mesocrystals were synthesized successfully by a two-step hydrothermal method. Observations using electron microscopy revealed that the obtained NaV2O5 mesocrystals were composed of nanobelts with the preferential growth direction of [010]. The precise crystal structure was further confirmed by Rietveld refinement and Raman spectroscopy. Based on analysis of crystal structure and microscopy, a reaction and growth mechanism, hydrolysis-condensation (oxolation and olation)-ion exchange-self-assembly, was proposed and described in detail. Furthermore, electrochemical measurements were used to analyze the Na-ions intercalation/deintercalation abilities in NaV2O5, and indicated that Na-ions were difficult to extract. Importantly, the DFT theoretical calculation results, which showed that the migration energy of Na-ions was so huge that migration of Na-ions was quite difficult, can explain and support well the results of the electrochemical measurements.