A novel nickel (I) complex (di(2,2'-(1-phenyl-1H-1,2,4-triazole-3,5-diyl)dipyridine))(dibromine) nickel(I)bromide ([Ni-N4]Br) exhibited extremely high efficiency toward the (de)hydrogenative alkylation of amines and alkyl heteroarenes by alcohols. The showing catalytic performance can be attributed...
Current methods of preparing formamides are limited by narrow substrate scopes and require harsh reaction conditions. Therefore, herein, the base-mediated formamidation of amines with CO (<2 bar) under mild conditions...
Reductive homocoupling transformations mediated by bases and TMSCN have been used as a strategy for synthesis of 1,2‐disubstituted ethanones. This protocol provides a method for synthesizing functionalized ethanones from aldehydes in one pot without transition metals.
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