A series of ZnFe2O4/expanded graphite composites (EG/ZF) were prepared by the chemical precipitation method. The structure, composition and morphology of the as-prepared samples were characterized. Taking methylene blue (MB) as the simulate organic pollutant, the influences of various factors on the decontamination of the as-samples and their reusing performance were researched. The results showed that the decontamination activity of the EG/ZF composite with mass ratio of EG to ZF equal to 0.8 reaches the maximum in the MB solution of pH = 5, and has good performance for repeated use. What’s more, the possible mechanism of decontamination was studied further.
In order to recover secondary iron-bearing dust, with converter sludge, mill scale, gravitational ash, casthouse ash as raw materials, high basicity carbon composite pellets are prepared to make iron nuggets through self-reduction at high temperature. The study demonstrates that: The effectively separation of iron and slag, naturally pulverization of the slag phase, and good surface quality of bigger, glosser and brighter iron nuggets can be obtained with reduction temperature 1400 °C,C/O molar ratio 1.1,as well as basicity above 1.8 in this process; The iron phase is not generated well and proportion of small size iron nuggets increases when C/O molar ratio is increased; With C/O molar ratio increases or temperature rises, CO generated increases in direct reduction, which strengthen the reducibility atmosphere in the pellets, beneficial to the processing of desulfuration and dephosphorization; Rising temperature accelerates the generation of molten iron, so that, the fixed carbon contacts with the molten iron longer, which increasing the carbon in iron nuggets. More carbon is provided for the carburizing reaction for the sake of increasing C/O molar ratio, as a result of making more carbon in iron nuggets.
The basic thermodynamic analysis of silicothermic reduction during direct alloying to smelting vanadium steel with V2O5 was discussed in this paper. The high-temperature carbon tube furnace and medium frequency vacuum induction furnace were used to study the phase compositions of the reduction products and the change law of the yield of vanadium when V2O5 was reduced by ferrosilicon. The research shows that the main phases of the silicothermic reduction products were VSi2、FeVO4 and Ca2SiO4 under the condition of using CaO to restrain the volatile of V2O5. Yield of vanadium was gradually improved with the increase of ferrosilicon during the direct alloying. The yield of vanadium in the steel is as high as 95.25% when the addition of ferrosilicon is 35%.
A unit of high-speed, large-scale, continuous, automated PCM, which is used for production process information management practice, is introduced in this paper. According to the practice of cold rolling equipment and "High-speed Management," advanced management methods and tools are embedded to process control, so as to achieve online control of "quality flow", real-time evaluation and improvement.
This paper mainly researches the volatile phenomenon of V2O5 at high-temperature and the appropriate additions to depress volatilization of V2O5 effectively during direct alloying with V2O5 to smelting vanadium steel. It shows that the volatilization loss of V2O5 is 4.34% when V2O5 is heated to 1600°C for 10 minutes. The reductant ferrosilicon and additives CaO can depress the volatilization of V2O5 effectively. The volatilization loss of V2O5 decreases to 1.55% at 1600°C when the mass ratio of ferrosilicon to V2O5 is 1:1. CaO can react with V2O5 to form calcium vanadate to decrease the activity of V2O5. The volatilization loss of V2O5 decreases to 1.82% with adding 48.0% CaO in the V2O5–CaO system at 1600°C. The volatilization loss of V2O5 with adding more than 30% CaO can decrease to 0.48% when keeping the mass ratio of ferrosilicon to V2O5 is 1:1.
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