A novel phosphor-doped titania in an anatase phase colored yellow was prepared by a simple modified sol–gel method with hypophosphorous acid as precursor. The as-prepared P-doped titania shows a narrower band gap than pure titania and an absorption tail in the visible range, which results in its effective photocatalytic degradation of 4-chlorophenol under visible-light ( >420 nm) irradiation.

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Uniformly carbon-covered alumina (CCA) was prepared via the carbonization of sucrose highly dispersed on the alumina surface. The CCA samples were characterized by XRD, XPS, DTA-TG, UV Raman, nitrogen adsorption experiments at 77 K, and rhodamine B (RB) adsorption in aqueous media. UV Raman spectra indicated that the carbon species formed were probably conjugated olefinic or polycyclic aromatic hydrocarbons, which can be considered molecular subunits of a graphitic plane. The N2 adsorption isotherms, pore size distributions, and XPS results indicated that carbon was uniformly dispersed on the alumina surface in the as-prepared CCA. The carbon coverage and number of carbon layers in CCA could be controlled by the tuning of the sucrose content in the precursor and impregnation times. RB adsorption isotherms suggested that the monolayer adsorption capacity of RB on alumina increased drastically for the sample with uniformly dispersed carbon. The as-prepared CCA possessed the texture of alumina and the surface properties of carbon or both carbon and alumina depending on the carbon coverage.

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Here we demonstrate the fabrication of novel, “quasi-bilayer” inverted organic photovoltaic devices using halogen-free solvents.

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