Reactive polymer coatings were synthesized via chemical vapor deposition (CVD) polymerization process. These coatings decouple surface design from bulk properties of underlying materials and provide a facile and general route to support thiol-ene and thiol-yne reactions on a variety of substrate materials. Through the reported technique, surface functions can be activated through a simple design of thiol-terminated molecules such as polyethylene glycols (PEGs) or peptides (GRGDYC), and the according biological functions were demonstrated in controlled and low-fouling protein adsorptions as well as accurately manipulated cell attachments.

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"Click" reactions provide precise and reliable chemical transformations for the preparation of functional architectures for biomaterials and biointerfaces. The emergence of a multiple-click reaction strategy has paved the way for a multifunctional microenvironment with orthogonality and precise multitasking that mimics nature. We demonstrate a multifaceted and route-controlled click interface using vapor-deposited functionalized poly-para-xylylenes. Distinctly clickable moieties of ethynyl and maleimide were introduced into poly-para-xylylenes in one step via a chemical vapor deposition (CVD) copolymerization process. The advanced interface coating allows for a double-click route with concurrent copper(i)-catalyzed Huisgen 1,3-dipolar cycloaddition (CuAAC) and the thiol-maleimide click reaction. Additionally, double-click reactions can also be performed in a cascade manner by controlling the initiation route to enable the CuAAC and/or thiol-yne reaction using a mono-functional alkyne-functionalized poly-para-xylylene. The use of multifaceted coatings to create straightforward and orthogonal interface properties with respect to protein adsorption and cell attachment is demonstrated and characterized.

Reducing residential and industrial electricity consumption has been a goal of governments around the world. Lighting sources account for a large portion of the whole energy/power consumption. Unfortunately, most of the existing installed lighting systems are ancient and have poor energy efficiency. Today, many manufacturers have introduced light-controlling systems into the current market. However, existing light controlling systems may not be successfully applied to buildings, streets, and industrial buildings due to high costs and difficult installation and maintenance. To combat this issue, this article presents an easy-to-install, low-cost, Master-Slave intelligent LED light-controlling system based on Internet of Things (IoT) techniques. The benefit of using the proposed system is that the brightness of the LED lights in the same zone can be changed simultaneously to save in energy consumption. Furthermore, the parameters of the LED lights can be directly set. Moreover, the related data are collected and uploaded to a cloud platform. In this article, we use 15 W T8 LED tubes (non-induction lamps) as a case study. When the proposed system is installed in a zone with few people, the energy-saving rate is as high as 90%. Furthermore, when 12 people pass by a zone within one hour, its energy-saving rate can reach 81%. Therefore, the advantages of using the proposed system include: (1) the original lamp holder can be retained; (2) no wiring is required; and (3) no server is set up. Moreover, the goal of energy saving can also be achieved. As a result, the proposed system changes the full-dark mode of the available sensor lamp to the low power low-light mode for standby. Further, it makes the sensor lamps in the same zone brighten or low-light way simultaneously, which can quickly complete large-scale energy-saving and convenient control functions of intelligent LED lighting controlling system.

The bottom-up patterning approach provides intrinsic advantages associated with unlimited resolution but is limited by the materials available for selection. A general and simple approach towards the selective deposition of poly-para-xylylenes is introduced in this communication. The chemical vapour deposition (CVD) of poly-para-xylylenes is inhibited on the high-energy surfaces of electrically charged conducting substrates. This technology provides an approach to selectively deposit poly-para-xylylenes irrespective of the substituted functionality and to pattern these polymer thin films from the bottom up.