The main objective of the article is to provide a thorough review of currently used AC-DC converters for alkaline and proton exchange membrane (PEM) electrolyzers in power grid or wind energy conversion systems. Based on the current literature, this article aims at emphasizing the advantages and drawbacks of AC-DC converters mainly based on thyristor rectifier bridges and chopper-rectifiers. The analysis is mainly focused on the current issues for these converters in terms of specific energy consumption, current ripple, reliability, efficiency, and power quality. From this analysis, it is shown that thyristors-based rectifiers are particularly fit for high-power applications but require the use of active and passive filters to enhance the power quality. By comparison, the association combination of the chopper-rectifier can avoid the use of bulky active and passive filters since it can improve power quality. However, the use of a basic chopper (i.e., buck converter) presents several disadvantages from the reliability, energy efficiency, voltage ratio, and current ripple point of view. For this reason, new emerging DC-DC converters must be employed to meet these important issues according to the availability of new power switching devices. Finally, based on the authors’ experience in power conversion for PEM electrolyzers, a discussion is provided regarding the future challenges that must face power electronics for green hydrogen production based on renewable energy sources.

To face the intensive use of natural gas and other fossil fuels to generate hydrogen, water electrolysis based on renewable energy sources (RES) seems to be a viable solution. Due to their fast response times, and high efficiency, proton exchange membrane electrolyzer (PEM EL) is the most suitable technology for long-term energy storage, combined with RES. Like fuel cells, the development of fit DC-DC converters is mandatory to interface the EL to the DC grid. Given that PEM EL operating voltages are quite low and to meet requirements in terms of output current ripples, new emerging interleaved DC-DC converter topologies seem to be the best candidates. In this work, a three-level interleaved DC-DC buck converter has been chosen to supply a PEM EL from a DC grid. Therefore, the main objective of this paper is to develop a suitable control strategy of this interleaved topology connected to a PEM EL emulator. To design the control strategy, investigations have been carried out on energy efficiency, hydrogen flow rate, and specific energy consumption. The obtained experimental results validate the performance of the converter in protecting the PEM EL during transient operations while guaranteeing correct specific energy consumption.

The in-house fuel cell test station.

The main purpose of this article is to provide a short review of proton exchange membrane electrolyzer (PEMEL) modeling used for power electronics control. So far, three types of PEMEL modeling have been adopted in the literature: resistive load, static load (including an equivalent resistance series-connected with a DC voltage generator representing the reversible voltage), and dynamic load (taking into consideration the dynamics both at the anode and the cathode). The modeling of the load is crucial for control purposes since it may have an impact on the performance of the system. This article aims at providing essential information and comparing the different load modeling.

In electrolyzers, Faraday’s efficiency is a relevant parameter to assess the amount of hydrogen generated according to the input energy and energy efficiency. Faraday’s efficiency expresses the faradaic losses due to the gas crossover current. The thickness of the membrane and operating conditions (i.e., temperature, gas pressure) may affect the Faraday’s efficiency. The developed models in the literature are mainly focused on alkaline electrolyzers and based on the current and temperature change. However, the modeling of the effect of gas pressure on Faraday’s efficiency remains a major concern. In proton exchange membrane (PEM) electrolyzers, the thickness of the used membranes is very thin, enabling decreasing ohmic losses and the membrane to operate at high pressure because of its high mechanical resistance. Nowadays, high-pressure hydrogen production is mandatory to make its storage easier and to avoid the use of an external compressor. However, when increasing the hydrogen pressure, the hydrogen crossover currents rise, particularly at low current densities. Therefore, faradaic losses due to the hydrogen crossover increase. In this article, experiments are performed on a commercial PEM electrolyzer to investigate Faraday’s efficiency based on the current and hydrogen pressure change. The obtained results have allowed modeling the effects of Faraday’s efficiency by a simple empirical model valid for the studied PEM electrolyzer stack. The comparison between the experiments and the model shows very good accuracy in replicating Faraday’s efficiency.

This article aims to develop a proton exchange membrane (PEM) electrolyzer emulator. This emulator is realized through an equivalent electrical scheme. It allows taking into consideration the dynamic operation of PEM electrolyzers, which is generally neglected in the literature. PEM electrolyzer dynamics are reproduced by the use of supercapacitors, due to the high value of the equivalent double-layer capacitance value. Steady-state and dynamics operations are investigated in this work. The design criteria are addressed. The PEM electrolyzer emulator is validated by using a 400-W commercial PEM electrolyzer. This emulator is conceived to test new DC-DC converters to supply the PEM ELs and their control as well, avoiding the risk to damage a real electrolyzer for experiment purposes. The proposed approach is valid both for a single cell and for the whole stack emulation.

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Proton exchange membrane fuel cell (PEMFC) is a device that converts hydrogen and oxygen to electricity. Power electronic converter is an important equipment to transfer energy from PEMFCs to loads properly. The PEMFC model suited for integrating with power electronic circuit simulation are the empirical and the equivalent circuit types. The gas diffusion layer is important part of the PEMFC. This part determines the limit condition of the PEMFC. However, the equivalent circuit model of the gas diffusion layer is not available. This paper proposes a dynamic equivalent circuit model for the GDL and its simulation.