The accretion of small bodies in the solar system is a fundamental process that was followed by planet formation. Chronological information of meteorites can constrain when asteroids formed. secondary carbonates show extremely old 53 mn-53 Cr radiometric ages, indicating that some hydrous asteroids accreted rapidly. However, previous studies have failed to define accurate mn/Cr ratios; hence, these old ages could be artefacts. Here we develop a new method for accurate mn/Cr determination, and report a reliable age of 4,563.4+0.4/-0.5 million years ago for carbonates in carbonaceous chondrites. We find that these carbonates have identical ages, which are younger than those previously estimated. This result suggests the late onset of aqueous activities in the solar system. The young carbonate age cannot be explained if the parent asteroid accreted within 3 million years after the birth of the solar system. Thus, we conclude that hydrous asteroids accreted later than differentiated and metamorphosed asteroids.

Carbonaceous meteorites are thought to be fragments of C-type (carbonaceous) asteroids. Samples of the C-type asteroid (162173) Ryugu were retrieved by the Hayabusa2 spacecraft. We measure the mineralogy, bulk chemical and isotopic compositions of Ryugu samples. They are mainly composed of materials similar to carbonaceous chondrite meteorites, particularly the CI (Ivuna-type) group. The samples consist predominantly of minerals formed in aqueous fluid on a parent planetesimal. The primary minerals were altered by fluids at a temperature of 37 ± 10°C, 5.2 − 0.8 + 0.7 (Stat.) − 2.1 + 1.6 (Syst.) million years after formation of the first solids in the Solar System. After aqueous alteration, the Ryugu samples were likely never heated above ~100°C. The samples have a chemical composition that more closely resembles the Sun’s photosphere than other natural samples do.

Abstract-We look at the relationship between the value of e 54 Cr in bulk meteorites and the time (after calcium-aluminum-rich inclusion, CAI) when their parent bodies accreted. To obtain accretion ages of chondrite parent bodies, we estimated the maximum temperature reached in the insulated interior of each parent body, and estimated the initial 26 Al/ 27 Al for this temperature to be achieved. This initial 26 Al/ 27 Al corresponds to the time (after CAI formation) when cold accretion of the parent body would have occurred, assuming 26 Al/ 27 Al throughout the solar system began with the canonical value of 5.2 9 10 À5 . In cases of iron meteorite parent bodies, achondrite parent bodies, and carbonaceous chondrite parent bodies, we use published isotopic ages of events (such as core formation, magma crystallization, and growth of secondary minerals) in each body's history to obtain the probable time of accretion. We find that e 54 Cr correlates with accretion age: the oldest accretion ages (1 AE 0.5 Ma) are for iron and certain other differentiated meteorites with e 54 Cr of À0.75 AE 0.5, and the youngest ages (3.5 AE 0.5 Ma) are for hydrated carbonaceous chondrites with e 54 Cr values of 1.5 AE 0.5. Despite some outliers (notably Northwest Africa [NWA] 011 and Tafassasset), we feel that the correlation is significant and we suggest that it resulted from late, localized injection of dust with extremely high e 54 Cr.

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We studied about 3400 presolar silicon carbide (SiC) grains from the Murchison CM2 meteorite for C-and Siisotopic compositions. Among these grains we identified 7 unusual or type C SiC (U/C) grains, characterized by isotopically heavy Si, and 36 supernova type X SiC grains, characterized by isotopically light Si. Selected U/C and X grains were also measured for S-, Mg-Al-, and Ca-Ti-isotopic compositions. We show that the U/C grains incorporated radioactive 44 Ti, which is evidence that they formed in the ejecta of Type II supernova (SNII) explosions. Abundances of radioactive 26 Al and 44 Ti are compatible with those observed in X grains. U/C and X grains carry light S with enrichments in 32 S of up to a factor of 2.7. The combination of heavy Si and light S observed in U/C grains is not consistent with abundance predictions of simple supernova models. The isotope data suggest preferential trapping of S from the innermost supernova zones, the production site of radioactive 44 Ti, by the growing silicon carbide particles. A way to achieve this is by sulfur molecule chemistry in the still unmixed ejecta. This confirms model predictions of molecule formation in SNII ejecta and shows that sulfur molecule chemistry operates in the harsh and hot environments of stellar explosions.

Recent dynamical models of Solar System evolution and isotope studies of rock-forming elements in meteorites have suggested that volatile-rich asteroids formed in the outer Solar System beyond Jupiter's orbit, despite being currently located in the main asteroid belt 1-4 . The ambient temperature under which asteroids formed is a crucial diagnostic to pinpoint the original location of asteroids and is potentially determined by the abundance of volatiles they contain. In particular, abundances and 13 C/ 12 C ratios of carbonates in meteorites record the abundances of carbonbearing volatile species in their parent asteroids. However, the sources of carbon for these carbonates remain poorly understood 5-8 . Here we show that the Tagish Lake meteorite contains abundant carbonates with consistently high 13 C/ 12 C ratios. The high abundance of 13 C-rich carbonates in Tagish Lake excludes organic matter as their main carbon source 5,9 . Therefore, the Tagish Lake parent body, presumably a D-type asteroid 10 , must have accreted a large amount of 13 C-rich CO2 ice. The estimated 13 C/ 12 C and CO2/H2O ratios of ice in Tagish Lake are similar to those of cometary ice 11,12 . Thus, we infer that at least some D-type asteroids formed in the cold outer Solar System and were subsequently transported into the inner Solar System owing to an orbital instability of the giant planets 1,3 .We performed in situ C-isotope measurements on individual grains of carbonate minerals, calcite (CaCO3) and dolomite (CaMg(CO3)2), in Tagish Lake, an ungrouped carbonaceous chondrite (CC) with a petrologic type of 2, indicating that it underwent aqueous alteration 13,14 (Methods). For comparison, we also conducted C-and O-isotope measurements on calcite grains in two Mighei-type carbonaceous chondrites (CM chondrites) with a petrologic type of 2, Nogoya and LaPaz Icefield (LAP) 031166. Due to the small grain size of Tagish Lake carbonates, we were not able to measure O isotopic ratios ( Supplementary Fig. 1). The  13 C and  18 O values ( 13 C/ 12 C and 17,18 O/ 16 O ratios are also expressed as  13 CVPDB and  17,18 OVSMOW, respectively, which represent permil, 10 -3 expressed as ‰, deviations from the isotopic ratios of standard materials: VPDB, Vienna Pee Dee Belemnite; VSMOW, Vienna Standard Mean Ocean Water) of CM carbonates are highly variable, ranging from approximately 20 to 80‰ and from approximately 15 to 40‰, respectively, and do not correlate with each other (Fig. 1a and Supplementary Table 1).The O-isotope data of CM carbonates plot on a single trend line (Fig. 1b), reflecting a change in formation temperatures and/or in the O isotopic ratios of fluids from which they formed. Therefore, the lack of correlation between  13 C and  18 O indicates that the variable  13 C values of CM carbonates must reflect isotopic heterogeneity of carbon sources (Methods). In contrast to CM carbonates, Tagish Lake carbonates have 478, 218-220 (2011). 28. Dauphas, N. The isotopic nature of the Earth's accreting material through time. Nature 541, 5...

Phobos and Deimos occupy unique positions both scientifically and programmatically on the road to the exploration of the solar system. Japan Aerospace Exploration Agency (JAXA) plans a Phobos sample return mission (MMX: Martian Moons eXploration). The MMX spacecraft is scheduled to be launched in 2024, orbit both Phobos and Deimos (multiple flybys), and retrieve and return >10 g of Phobos regolith back to Earth in 2029. The Phobos regolith represents a mixture of endogenous Phobos building blocks and exogenous materials that contain solar system projectiles (e.g., interplanetary dust particles and coarser materials) and ejecta from Mars and Deimos. Under the condition that the representativeness of the sampling site(s) is guaranteed by remote sensing observations in the geologic context of Phobos, laboratory analysis (e.g., mineralogy, bulk composition, O-Cr-Ti isotopic systematics, and radiometric dating) of the returned sample will provide crucial information about the moon’s origin: capture of an asteroid or in-situ formation by a giant impact. If Phobos proves to be a captured object, isotopic compositions of volatile elements (e.g., D/H, 13C/12C, 15N/14N) in inorganic and organic materials will shed light on both organic-mineral-water/ice interactions in a primitive rocky body originally formed in the outer solar system and the delivery process of water and organics into the inner rocky planets.

We report C, Si, and S isotope measurements on 34 presolar silicon carbide grains of Type AB, characterized by 12 C/ 13 C < 10. Nitrogen, Mg-Al-, and Ca-Ti-isotopic compositions were measured on a subset of these grains. Three grains show large 32 S excesses, a signature that has been previously observed for grains from supernovae (SNe). Enrichments in 32 S may be due to contributions from the Si/S zone and the result of S molecule chemistry in still unmixed SN ejecta or due to incorporation of radioactive 32 Si from C-rich explosive He shell ejecta. However, a SN origin remains unlikely for the three AB grains considered here, because of missing evidence for 44 Ti, relatively low 26 Al/ 27 Al ratios (a few times 10 -3 ), and radiogenic 32 S along with low 12 C/ 13 C ratios. Instead, we show that born-again asymptotic giant branch (AGB) stars that have undergone a very-late thermal pulse (VLTP), known to have low 12 C/ 13 C ratios and enhanced abundances of the light s-process elements, can produce 32 Si, which makes such stars attractive sources for AB grains with 32 S excesses. This lends support to the proposal that at least some AB grains originate from born-again AGB stars, although uncertainties in the born-again AGB star models and possible variations of initial S-isotopic compositions in the parent stars of AB grains make it difficult to draw a definitive conclusion.