Optical properties of pure and doped poly(vinyl chloride) (PVC) films, prepared by using casting technique, with different nanosize zinc oxide (ZnO) concentrations (1–20) wt% have been studied. Parameters such as extinction coefficient, refractive index, real and imaginary parts, Urbach energy, optical conductivity, infinitely high frequency dielectric constant, and average refractive index were studied by using the absorbance and transmittance measurement from computerized UV-visible spectrophotometer (Shimadzu UV-1601 PC) in the spectral range 200–800 nm. This study reveals that the optical properties of PVC are affected by the doping of ZnO where the absorption increases and transmission decreases as ZnO concentration increases. The extinction coefficient, refractive index, real and imaginary parts, infinitely high frequency dielectric constant, and average refractive index values were found to increase with increasing impurity percentage. The Urbach energy values are found to be decreasing with increasing ZnO concentration. The optical conductivity increased with photon energy after being doped and with the increase of ZnO concentration.

Films of PMMA and PMMA doped with NiCl 2 with different contents were prepared using the casting technique. The optical properties of all films were investigated using spectrophotometric measurements of absorbance and transmittance in the wavelength range 200-800 nm. The change of the calculated values of the optical energy gaps with increasing NiCl 2 content has been interpreted in terms of the structural modifications of the PMMA matrix. The optical energy gap decreased from 3.6 to 3.05 eV with increasing the NiCl 2 concentration to 0.4%. The effect of doping on the optical constants of films such as refractive index, extinction coefficient, real and imaginary parts of dielectric constant, optical conductivity, and skin depth has been reported. All these constants were increased with increasing NiCl 2 concentration with the exception of skin depth which is different result.

The effect of continuous CO2laser radiation on the optical properties of pure polyvinyl chloride and doped of ZnO nanoparticles with two different concentrations (10, 15%) has been investigated. All samples were prepared using casting method at room temperature. Optical properties (absorption, transmission, absorption coefficient, extinction coefficient, refractive index, and optical conductivity) of all films after CO2laser irradiated have been studied as a function of the wavelength in the range (200–800) nm for three energies (300, 400 and 500 mJ). It has been found that the transmission, energy gap, and refractive index increase with increasing laser energy. The values of absorption, Urbach energy, absorption coefficient, extinction coefficient, and optical conductivity were decreased.

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Pure and Antimony Trioxide Sb2O3 doped PMMA films were prepared by the casting method. Optical absorption measurements in the wavelength range 200-800 nm were studied by using a computerized UVVis spectrophotometer (Shimadzu UV-1601 PC) and these confirmed that PMMA films have a direct band gap that decreases from 5.15 to 4.66 eV as the doping concentration increases to 5wt%. The increase in the density of localized states from 8.9 to 74.5 meV causes an expansion in the Urbach tail and consequently decreases the energy gap. The dispersion of the refractive index was analyzed using the concept of a single oscillator. The values of the single oscillator energy were 32.70, 13.59, 7.06, and 4.58 eV, while the dispersion energy values were 4.36, 49.04, 21.76 and 14.15 eV for the pure, and 3%, 4% and 5% Sb2O3 for the doped PMMA films respectively. The single-term Sellmeier were determined, and the average oscillator position was investigated, the value of which decreased with increasing doping concentration. The value of average oscillator strength increased with increasing Sb2O3 concentration to 5wt%. Skin depth and optical conductivity could be calculated, and results show a decrease in Skin depth with an increasing impurity percentage, but an increase of optical conductivity with greater impurity

Pure and Fe citrate doped poly (vinyl Alcohol) PVA films with different concentrations (1, 1.0, 0.0, and 2) wt% were prepared by using casting technique. Optical absorption measurements in the wavelength range 211-011 nm were studied and confirmed that PVA films have an direct band gap that decreased from 0..5 to ..54eV as the doping concentration increases to 2wt%. Optical constants such as absorption coefficient, refractive index, Extinction coefficient real and imaginary parts of dielectric constant have been studied; results show that the optical constants of the pure PVA films were increased after doping and with increasing impurity concentration. Urbach energy and optical conductivity were increases with the increasing of impurity concentration. The increase in the density of localized states Eu from 1445 to 1494eV causes an expanding in the Urbach tail and consequently decreases the energy gap.

optical properties of pure poly(vinyl Alcohol) films and poly(vinyl Alcohol) doped with methyl red were study, different percentage prepared with constant thickness using casting technique. Absorption, Transmission spectra have been recorded in order to study the optical parameters such as absorption coefficient, energy gap, refractive index, Extinction coefficient and dispersion parameters were measured in the wavelength range (200-800)nm. This study reveals that the optical properties of PVA affect by increasing the impurity concentration.

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