Concentrated Solar Power (CSP) technology captures solar radiation and converts it into heat for electricity production. It has received an increasing attention because integrated thermal energy storage (TES) systems can largely enhancing the reliability and the dispatchability. Over the last decade, low-cost single storage tank based on the thermocline technology becomes an alternative to commonly-used two-tank TES system. However, the improper inlet/outlet manifolds may cause the strong mixing of hot and cold fluids and disturb the temperature stratification, resulting in reduced thermal performances of the storage tank. This study aims at solving the flow maldistribution problem in the single-tank thermocline storage system by appropriately structuring the inlet/outlet manifolds. The technical solution is based on the insertion of optimized perforated baffles in the manifolds. 2D Computational fluid dynamics simulations were performed to calculate the transient flow and temperature profiles in the storage tank during the charging and discharging operations. The optimal size distribution of orifices on the upper baffle has been determined for homogenizing passage times of the thermal front, so as to enhance the temperature stratification. A novel intermediate evaluation indicator was introduced to characterize the real-time thermal behavior, which could reduce the computational cost of the optimization problem by a factor of 6 at least. Numerical results shown that the proposed optimization algorithm could significantly improve the thermal performances, indicated by the increased values of charging/discharging efficiency, the capacity ratio and the overall efficiency, ex., the fully charging efficiency be increased by 29% by comparing the unstructured manifold geometry and the one with optimized baffles. The parametric study on certain geometry and operating factors also demonstrated that the proposed method for flow distribution optimization was robust, effective and efficient.

International audienceThis study focused on the removal of antibiotic by coupling of heterogeneous photocatalysis with ozonation and hydrogen peroxide. The main objective was to intensify the efficiency of photocatalytic activity for better and faster antibiotic elimination/mineralization in wastewater. To fulfill this purpose a photocatalytic process based on falling film reactor was designed and optimized. The effects of operating parameters such as wastewater flow rate in the falling film reactor, the presence of an oxidizing agent (H2O2 and O3), inlet concentrations, including catalyst dosage and light intensity were investigated and discussed. Experiments were mainly conducted with Flumequine and Clarithromycin. The first molecule (Flumequine) will serve as an example of fluoroquinolone antibiotics and the second (Clarithromycin) as an example of macrolide antibiotics. Experimentally, the results have shown interesting degradation and mineralization efficiency (on the order of 94% for degradation and 76% for mineralization). Evidence for redox catalysis was shown using X-ray photoelectron spectroscopy (XPS) before and after pollutant degradation. Moreover, special attention was also paid to identify the reaction products and the plausible degradation pathway during Flumequine degradation

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Thermal energy storage (TES) system plays an essential role in the utilization and exploitation of renewable energy sources. Over the last two decades, single-tank thermocline technology has received much attention due to its high cost-effectiveness compared to the conventional two-tank storage systems. The present paper focuses on clarifying the performance indicators and the effects of different influencing factors for the thermocline TES systems. We collect the various performance indicators used in the existing literature, and classify them into three categories: (1) ones directly reflecting the quantity or quality of the stored thermal energy; (2) ones describing the thermal stratification level of the hot and cold regions; (3) ones characterizing the thermo-hydrodynamic features within the thermocline tanks. The detailed analyses on these three categories of indicators are conducted. Moreover, the relevant influencing factors, including injecting flow rate of heat transfer fluid, working temperature, flow distributor, and inlet/outlet location, are discussed systematically. The comprehensive summary, detailed analyses and comparison provided by this work will be an important reference for the future study of thermocline TES systems.