The destructive interference of wavefunctions in a kagome lattice can give rise to topological flat bands (TFBs) with a highly degenerate state of electrons. Recently, TFBs have been observed in several kagome metals, including Fe3Sn2, FeSn, CoSn, and YMn6Sn6. Nonetheless, kagome materials that are both exfoliable and semiconducting are lacking, which seriously hinders their device applications. Herein, we show that Nb3Cl8, which hosts a breathing kagome lattice, is gapped out because of the absence of inversion symmetry, while the TFBs survive because of the protection of the mirror reflection symmetry. By angle-resolved photoemission spectroscopy measurements and first-principles calculations, we directly observe the TFBs and a moderate band gap in Nb3Cl8. By mechanical exfoliation, we successfully obtain monolayer Nb3Cl8, which is stable under ambient conditions. In addition, our calculations show that monolayer Nb3Cl8 has a magnetic ground state, thus providing opportunities to study the interplay among geometry, topology, and magnetism.

Topological semimetals have attracted much attention and become a hot subject in condensed matter physics, and single crystal growth is the basis of the physical investigation on these materials. At present, the research of topological materials has formed a cooperation circle:presenting materials by theoretical calculation; single crystal growth; verification by experiments on single crystals. Single crystal growth has become a bridge between theory and experiment. Here in this paper, we introduce the single crystal growth of the topological semimetals presented in recent years, including topological Dirac semimetals, Weyl semimetals, Node-Line semimetals and other new classes of topological materials. The detailed growth methods are summarized in this paper for each material.