Cyclic oligomers of caprolactam were isolated from a multilayered polyolefin plastic film containing a nylon-6 layer and subsequently characterized. Nylon-6 was extracted with aqueous solutions and the levels of the oligomers were measured in the resulting extracts. Oligomers up to n ϭ 5 were present at high and comparable levels in all the nylon-6 extracts. The levels of the oligomers dropped off rapidly with increased compound size after n ϭ 5, with the heptamer being barely observable in the extract chromatograms. The effect of extracting solution pH on the compound's concentration in the extract was small, except for the monomer, whose accumulation was significantly decreased at low pH.
The design of propellant loading systems for present-day missiles involves the design of pipelines that can carry cryogenic fluids and requires an additional consideration beyond the conventional analyses for flexibility and dead weight. Because of varying flow conditions and boil-off, these cryogenic lines experience varying fill levels and concomitant temperature gradients which cause these lines to bow; i.e., to assume a uniform curvature of circular arc. If constrained, the thermal-stress distributions which are generated by the temperature gradients will have superposed on them additional stresses, which result from the action of the support constraints. This combination of stresses may be critical and/or the loads on the supports may be excessive. The following analysis investigates these bowing effects, thermal stresses, and indicates the support problems entailed.
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