The Ti-6Al-4V alloy was nitrided at 950 °C for 8 h by heating under atmospheric nitrogen in order to improve its surface hardness and oxidation resistance. Nitrogen diffused into the Ti6Al4V alloy, and formed ~40 μm-thick coating consisting of TiN as the major phase and Ti2N as the minor one. Nitriding increased the surface microhardness through the strengthening effect of interstitial nitrogen and the formation of nitrides. Oxidation at 700 °C for 10 h formed a superficial TiO2 layer on the coating.

The carbon steel formed the thick, somewhat porous, loosely adherent iron oxide scale when oxidized at 500-800

Carbonate rocks are believed to be proven hydrocarbon reservoirs and are found in various basins of Pakistan including Lower Indus Basin. The carbonate rock intervals of the Jakkher Group from Paleocene to Oligocene age are distributed in south-western part of Lower Indus Basin of Pakistan. However, there are limited published petrophysical data sets on these carbonate rocks and are essential for field development and risk reduction. To fill this knowledge gap, this study is mainly established to collect the comprehensive high quality data sets on petrophysical properties of carbonate rocks along with their mineralogy and microstructure. Additionally, the study assesses the impact of diagenesis on quality of the unconventional tight carbonate resources. Experimental techniques include Scanning Electronic Microscopy (SEM), Energy-Dispersive X-ray Spectroscopy (EDS), and X-ray diffraction (XRD), photomicrography, Helium porosity and steady state gas permeability. Results revealed that the porosity was in range of 2.12 to 8.5% with an average value of 4.5% and the permeability was ranging from 0.013 to 5.8mD. Thin section study, SEM-EDS, and XRD analyses revealed that the samples mostly contain carbon (C), calcium (Ca), and magnesium (Mg) as dominant elemental components.The main carbonate components observed were calcite, dolomite, micrite, Ferron mud, bioclasts and intermixes of clay minerals and cementing materials. The analysis shows that: 1) the permeability and porosity cross plot, the permeability and slippage factor values cross plots appears to be scattered, which showed weaker correlation that was the reflection of carbonate rock heterogeneity. 2) The permeability and clay mineralogy cross plots have resulted in poor correlation in these carbonate samples. 3) Several diagenetic processes had influenced the quality of carbonates of Jakkher Group, such as pore dissolution, calcification, cementation, and compaction. 4) Reservoir quality was mainly affected by inter-mixing of clay, cementation, presence of micrite muds, grain compactions, and overburden stresses that all lead these carbonate reservoirs to ultra-tight reservoirs and are considered to be of very poor quality. 5) SEM and thin section observations shows incidence of micro-fractures and pore dissolution tended to improve reservoir quality.

The production from shale gas reservoirs has significantly increased due to technological advancements. The shale gas reservoirs are very heterogeneous and the heterogeneity has a significant effect on the quality and productivity of reservoirs. Hence, it is essential to study the behavior of such reservoirs for accurate modelling and performance prediction. To evaluate the impact of fracture parameters on shale gas reservoir productivity using CMG (Computer Modelling Group) stars simulation software was the main objective of this study. In this paper, a comprehensive analysis considering an example shale gas reservoir was conducted for production performance analysis considering uniform and non-uniform fractures configurations. Several simulations were performed by considering the multi-stage hydraulically fractured reservoir. The sensitivities conducted includes the different cases of moderate and severe heterogeneity along with variable fractures half-length, effect of changing fracture spacing, variable fracture conductivities. The simulation results showed that by increasing conductivity of fracture increases the gas production rate significantly. Moreover, cases of reservoir permeability heterogeneity were analyzed which show the significant effect on gas rate and on cumulative gas production. The results of this study can be used to improve the effectiveness in designing and developing of shale gas reservoirs and also to improve the accuracy of analyzing heterogeneous shale gas reservoir performance.