(TBAA-n) crystallize in the f$lowing space groups: TBAA-0: monoclinic, P 2,/c, u = 7.656(3), h = 6.073(1), c = 16.403(7)/. B = 91.60(2)"; TBAA-1: monoclinic, P 2,/n, u = 6.0426(11). h = 7.84171(4), c = 18.2147(31 A, B = 92.32(1)"; TBAA-2: orthorhombic, P bcn, ( I = 20.9390(8), h = R = 0.029, 0.044, and 0.049, respectively.Despite the different conformation of the terminal phenyl rings relative to the central core of the coplanar azomethine groups and the phenyl ring, the molecular packing of the three compounds obeys the same principles in forming the crystal structure.14.8876 (7)
The three homologue compounds with the general formula CnHln+ -COO -C6H, -C6H, -OOC-C,H,,+ (SYM-n) crystallize in the following space groups: SYM-1: triclinic, P i , a = 7.400(6),
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