The Remote Sensing Group at the University of Arizona has used ground-based test sites for the vicarious calibration of airborne and satellite-based sensors, of which the Railroad Valley Playa in north central Nevada has played a key role. This work presents a cross comparison of five satellite-based sensors that all imaged this playa on July 16, 2001. These sensors include the Advanced Land Imager and Hyperion on the Earth Observer-1 platform, the Landsat-7 Enhanced Thematic Mapper Plus (ETM+), Terra's Moderate Resolution Imaging Spectroradiometer, and Space Imaging's Ikonos. The approach atmospherically corrects the ETM+ data to derive surface reflectance for a 1 km 1 km area of the playa and then uses these reflectances to determine a hyperspectral at-sensor radiance for each of the sensors taking into account the changes in solar zenith angle due to any temporal differences in the overpass times as well as differences in the view angles between the sensors. Results show that all of the sensors agree with ETM+ to within 10% in the solar reflective for bands not affected by atmospheric absorption. ETM+, MODIS, and ALI agree in all bands to better than 4.4% with better agreement in the visible and near infrared. Poorer agreement between Hyperion and other sensors appears to be due partially to poorer signal to noise ratio in the narrowband Hyperion datasets.

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Both plant physiology and atmospheric chemistry are substantially altered by the emission of volatile isoprenoids (VI), such as isoprene and monoterpenes, from plant leaves. Yet, since gaining scientific attention in the 1950’s, empirical research on leaf VI has been largely confined to laboratory experiments and atmospheric observations. Here, we introduce a new field instrument designed to bridge the scales from leaf to atmosphere, by enabling precision VI detection in real time from plants in their natural ecological setting. With a field campaign in the Brazilian Amazon, we reveal an unexpected distribution of leaf emission capacities (EC) across the vertical axis of the forest canopy, with EC peaking in the mid-canopy instead of the sun-exposed canopy surface, and moderately high emissions occurring in understory specialist species. Compared to the simple interpretation that VI protect leaves from heat stress at the hot canopy surface, our results encourage a more nuanced view of the adaptive role of VI in plants. We infer that forest emissions to the atmosphere depend on the dynamic microenvironments imposed by canopy structure, and not simply on canopy surface conditions. We provide a new emissions inventory from 52 tropical tree species, revealing moderate consistency in EC within taxonomic groups. We highlight priorities in leaf volatiles research that require field-portable detection systems. Our self-contained, portable instrument provides real-time detection and live measurement feedback with precision and detection limits better than 0.5 nmolVI m–2leaf s–1. We call the instrument ‘PORCO’ based on the gas detection method: photoionization of organic compounds. We provide a thorough validation of PORCO and demonstrate its capacity to detect ecologically driven variation in leaf emission rates and thus accelerate a nascent field of science: the ecology and ecophysiology of plant volatiles.