Some expressions for the time evolution of quantum-mechanical systems with Hamiltonians periodic in time, derivable from the work of Shirley and applied by Young, Deal, and Kestner and Haeberlen and Waugh -all for finite-basis-set systems -are derived for a general system (possibly infinite Hilbert space). These results suggest a new type of approximation to the time-evolution operator, one which is exact at multiples of the period of the Hamiltonian. Comparison is made to an exactly soluble problem, namely, a nonrelativistic hydrogen atom in a circularly polarized monochromatic field.
A method is presented for obtaining the various terms in the Rayleigh–Schrödinger perturbation theory to arbitrary order by means of diagrams. The prescription for obtaining the Nth-order correction to a particular zero-order eigenvector is to construct all diagrams of a certain type and associate an operator with each diagram. The method provides for the easy construction and display of Rayleigh–Schrödinger perturbation-theory corrections. The relationship of the present method to other work is discussed.
An alternative to the Magnus expansion in time-dependent quantum mechanical perturbation theory is presented. An exponential form of the time-development operator, given as the exponential of a sum of products of integrals well known in time-dependent quantum mechanics, is derived from the standard perturbation expansion. The derivation is simple and the form of the terms in the exponential is so straightforward that the Nth order term can be written by inspection. The standard Magnus terms can be obtained by rearrangement of the terms of the new expansion probably easier than they can be obtained by iteration of the original equations. A proof by induction is presented to establish the form of the Nth term and it is shown how the new expansion terms relate to the Magnus terms. Some apparent differences between Magnus terms in the literature are resolved.
General and greatly simplified methods are presented for calculating terms in the exponent in Magnus and Magnus-like expansions to first order in a ‘‘small’’perturbation and to infinite order in the overall Hamiltonian in the Schrödinger representation. These techniques are applied to four simple but important models and it is shown that in each case the Magnus exponent diverges for some range of the parameters of the model. This result casts serious doubt on the utility of the Magnus expansion in the Schrödinger representation. Several of the problems are also treated in the interaction representation giving results which converge throughout the useful range of parameters. There is no evidence that a similar question exists in this representation.
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