We report the characteristics of complementary organic ring oscillators. The shortest delay time measured is 38 μs per stage that corresponds to a 2.63 kHz oscillation frequency. The active material in the n-channel transistors is copper hexadecafluorophthalocyanine and that in the p-channel transistors is an oligothiophene/oligothiophene derivative.

Low-dielectric constant (low-k) material is critical for advanced FinFET technology parasitic capacitance reduction to enable lowpower and high-performance applications. Silicon Oxycarbonnitride (SiOCN) is one of the most promising low-k materials for FinFET gate sidewall spacer. The k value of SiOCN can be controlled in the range of 4.1-5.2 by modifying the chemical contents during the deposition process. However, the integration of SiOCN with k value lower than 5.2 for advanced FinFET technology faces substantial challenges associated with the material damage from subsequent manufacturing processes. Here, the authors demonstrate a hybrid low-k spacer scheme on a fully integrated 7 nm FinFET technology platform, in which SiOCN with k value of 4.5 was successfully integrated along the sidewalls of the gate electrode as spacer while retaining the structural integrity and dielectric properties. Device characterisation on the hybrid low-k spacer scheme (k = 4.5) demonstrated 12/11% reduction in P/NFET overlap capacitance (C OV) and 3% reduction in ring oscillator effective capacitance (C EFF) in comparison to the baseline reference using SiOCN with k value of 5.2 as spacer. Furthermore, reliability characterisation confirmed the dielectric breakdown voltage (V BD) and leakage current (I LKG) of the hybrid low-k spacer (k = 4.5) were comparable to the baseline reference (k = 5.2), meeting the technology requirements.