Layered molybdenum disulfide (MoS2) is deposited by microwave heating on a reduced graphene oxide (RGO). Three concentrations of MoS2 are loaded on RGO, and the structure and morphology are characterized. The first layers of MoS2 are detected as being directly bonded with the oxygen of the RGO by covalent chemical bonds (Mo‐O‐C). Electrochemical characterizations indicate that this electroactive material can be cycled reversibly between 0.25 and 0.8 V in 1 m HClO4 solution for hybrids with low concentrations of MoS2 layers (LCMoS2/RGO) and between 0.25 and 0.65 V for medium (MCMoS2/RGO) and high concentrations (HCMoS2/RGO) of MoS2 layers on graphene. The specific capacitance measured values at 10 mV s−1 are 128, 265, and 148 Fg−1 for the MoS2/RGO with low, medium, and high concentrations of MoS2, respectively, and the calculated energy density is 63 W h kg−1 for the LCMoS2/RGO hybrid. This supercapacitor electrode also exhibits superior cyclic stability with 92% of the specific capacitance retained after 1000 cycles.

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The reduction of SO 2 on activated carbon was studied in the range of 600-700 C in a differential reactor under steady-state conditions and under chemically controlled kinetics. Initial rates of carbon conversion and gas reagent were calculated from the mass balance of the gaseous products. The kinetics was first-order with respect to carbon and first-order with respect to the partial pressure of SO 2 . The activation parameters were ÁH 6 ¼ ¼ 21.5 kcal mol À1 and ÁS 6 ¼ ¼ À211 cal mol À1 K À1 . The activated carbon was ca. 10 5 times more reactive than graphite, and determined by the enthalpy of activation. The main reaction products were CO 2 and sulfur. CO and COS were produced from consecutive reactions of the primary products. During the pre-steady state, the sulfur content of the carbon increased to a plateau where the reaction reached the steady state condition. This sulfur was shown to be chemically bound to the carbon matrix and represents the stable reactive intermediates of the reduction of SO 2 . The XPS spectrum of the residual carbon C(S) showed two forms of sulfur bound to carbon: non-oxidized sulfur (sulfide and/or disulfide) and oxidized sulfur (sulfone, sulfoxide, sulfenate, sulfinate). The sulfur intermediates C(S) reacted with SO 2 at the same rate as pure activated carbon and with CO 2 to produce SO 2 by the reverse reaction. The reaction of C(S) with CO produced COS.

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