Hydrous ruthenium oxide (RuO2·xH2O or RuO
x
H
y
) is a mixed proton−electron conductor which could be
used in fuel cells and ultracapacitors. Its charge-storage (pseudocapacitance) and electrocatalytic properties
vary with water content and are maximized near the composition RuO2·0.5 mol % H2O. We studied the
atomic structure of RuO2·xH2O as a function of water content from x = 0.84 to 0.02 using X-ray diffraction
and atomic pair density function (PDF). Even though the diffraction patterns of samples containing 0.84 to
0.35 mole of water are suggestive of “amorphous” structures, the PDF analysis clearly shows that up to 0.7
nm, the short-range atomic structure of all of these RuO2·xH2O samples resembles that of the anhydrous
rutile RuO2 structure. We conclude that RuO2·xH2O is a composite of anhydrous rutile-like RuO2 nanocrystals
dispersed by boundaries of structural water associated with Ru−O. Metallic conduction is supported by the
rutile-like nanocrystals, while proton conduction is facilitated by the structural water along the grain boundaries.
This structural picture explains the charge-storage and electrocatalytic properties of RuO2·xH2O in terms of
competing percolation networks of metallic and protonic conduction pathways, that vary in volume as a
function of the water content of the RuO2·xH2O. The control and optimization of electron and proton conducting
volumes and pathways will lead to improved performance and guide the design of new materials.
When a stress is applied on a metallic glass it deforms following Hook's law. Therefore it may appear obvious that a metallic glass deforms elastically. Using x-ray diffraction and anisotropic pair-density function analysis we show that only about 3/4 in volume fraction of metallic glasses deforms elastically, whereas the rest of the volume is anelastic and in the experimental time scale deform without resistance. We suggest that this anelastic portion represents residual liquidity in the glassy state. Many theories, such as the free-volume theory, assume the density of defects in the glassy state to be of the order of 1%, but this result shows that it is as much as a quarter.
Using neutron pair distribution function analysis over the temperature range from 1000 to 15 K, we demonstrate the existence of local polarization and the formation of medium-range, polar nanoregions (PNRs) with local rhombohedral order in a prototypical relaxor ferroelectric Pb(Mg(1/3)Nb(2/3))O3. We estimate the volume fraction of the PNRs as a function of temperature and show that this fraction steadily increases from 0% to a maximum of approximately 30% as the temperature decreases from 650 to 15 K. Below T approximately 200 K the volume fraction of the PNRs becomes significant, and PNRs freeze into the spin-glass-like state.
Metallic glasses are known for their outstanding mechanical strength. However, the microscopic mechanism of failure in metallic glasses is not well-understood. In this article we discuss elastic, anelastic and plastic behaviors of metallic glasses from the atomistic point of view, based upon recent results by simulations and experiments. Strong structural disorder affects all properties of metallic glasses, but the effects are more profound and intricate for the mechanical properties. In particular we suggest that mechanical failure is an intrinsic behavior of metallic glasses, a consequence of stress-induced glass transition, unlike crystalline solids which fail through the motion of extrinsic lattice defects such as dislocations.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.