Ethylene, propylene, and styrene oxides have been polymerized by a range of metal halide catalysts, high molecular weight products being obtained from the two firstnamed. The limited quantitative evidence presented is consistent with the view that these polymerizations proceed by a coordinate propagation mechanism. The effective catalyst for this stage is essentially a metal alkoxide, formed in an initial cationic polymerization in which a small number of monomer units are attached to the metal atom. The propylene oxide polymers generally contain a fraction of crystalline material, but the proportion of this can be reduced practically to zero (with FeCl3 catalysis) by careful exclusion of water.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.