No abstract

The cyclo-(P4tBu3) synthon [Li{cyclo-(P4tBu3)}(thf)(tmeda)] (1) (thf = tetrahydrofuran, tmeda = N,N,N′,N′-tetramethylethane-1,2-diamine) is readily accessible in a one-pot synthesis from P4 and LitBu. The use of 1 as a cyclo-(P4tBu3) building block enables the rational...

The reaction of tetra-tert-butylcyclotetraphosphane cyclo-(PtBu)4 (L) with one to four equivalents [AuCl(tht)] (tht = tetrahydrothiophene) leads to the gold(I) complexes [(AuCl)nL] (n = 1–4, 1–4) in which the ligand coordinates...

Hepta-tert-butylnonaphosphane {cyclo-(P4tBu3)}2PtBu was employed as a ligand in transition metal complexes of iron(0) (1), cobalt(–I) (2), copper(I) (3) and rhodium(I) (4), which are readily formed in moderate to good yields,...

Correction for ‘Facile synthesis of cyclo-(P4tBu3)-containing oligo- and pnictaphosphanes’ by Volker Jens Eilrich et al., Dalton Trans., 2021, 50, 14144–14155, DOI: 10.1039/D1DT02639A.