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Salinity and acidity have affected several hundred million hectares of land throughout the globe which poses a major threat to global food security and biodiversity. Application of organic amendments for salt-affected soils has been identified as one of the most effective ways to mitigate salinity-induced problems and considered as a green technique offering twin benefits of waste load reduction and land reclamation. However, studies on reclaiming acidic-salt affected soils are limited. Therefore, this study aimed to determine the reclamation potential of biochars and organic amendments involving Gliricidia sepium biochar produced at 300 °C, 500 °C, and 700 °C, green waste compost, and municipal sewage sludge at three different amendment ratios, 1.0%, 2.5% and 5.0%. The incubation experiment was conducted for a 4-month period with different amendment ratios applied to the coastal acidic-salt affected soil. Subsamples were extracted from incubation pots after 1 and 4 months and analyzed for soil chemical parameters (pH, EC, NO 3 − , PO 4 3− , total organic carbon, cation exchange capacity, sodium adsorption ratio, exchangeable sodium percentage) and microbial enzyme activity (catalase activity, and acid-and alkaline phosphatase activity). All organic amendments demonstrated enhancement of the soil properties in a significant manner. However, increasing incubation time and amendment ratio increase the changes of soil parameters by a great percentage. Therefore, the maximum amendment ratio of 5.0% and 4 months of incubation period rendered a significant improvement in the reclamation of acidic-salt affected soil. However, the biochar produced at 500 °C contributed the maximum towards the improved physicochemical and biochemical profile of acidic-salt affected soil, making it the most promising organic amendment for the reclamation of acidic-salt affected soil. The overall reclamation efficiency of organic amendments registered the following order of variation: 700 BC < Sludge < 300 BC < Compost < 500 BC.

Hydrometallurgical processes for heavy metal recovery from industrial sludgesHydrometallurgical approaches have been successfully employed for metal separation and recovery from various types of waste materials. Therefore, hydrometallurgy is a promising technology for metal recovery and the removal of potentially toxic heavy metals found in industrial sludge.However, a comprehensive review that focuses on the heavy metal recovery from industrial sludge using hydrometallurgical approaches has not been conducted in the recent past. The present review discusses the capacity of hydrometallurgical techniques in recovering heavy metals sourced from different types of industrial sludges, highlighting recent scientific findings. Hydrometallurgical approaches primarily consist of three process stages: metal dissolution, concentration and purification, and metal recovery. The chemical characteristics of industrial sludge, including the type, concentration and speciation of heavy metals, directly impact selection of the best recovery method. Solvent extraction, ion-exchange, and adsorption are the major techniques employed in concentration and purification, whereas electrodeposition and precipitation are the main methods used in metals recovery. Future research should focus on the development of more efficient and environmentally-friendly methods for metal dissolution from industrial sludges contaminated with multiple metals, while increasing selectivity and energy use efficiency in the concentration and purification, and recovery steps.

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