The nonlinear rheology of a soft glassy material is captured by its constitutive relation, shear stress versus shear rate, which is most generally obtained by sweeping up or down the shear rate over a finite temporal window. For a huge amount of complex fluids, the up and down sweeps do not superimpose and define a rheological hysteresis loop. By means of extensive rheometry coupled to time-resolved velocimetry, we unravel the local scenario involved in rheological hysteresis for various types of well-studied soft materials. We introduce two observables that quantify the hysteresis in macroscopic rheology and local velocimetry, respectively, as a function of the sweep rate δt(-1). Strikingly, both observables present a robust maximum with δt, which defines a single material-dependent time scale that grows continuously from vanishingly small values in simple yield stress fluids to large values for strongly time-dependent materials. In line with recent theoretical arguments, these experimental results hint at a universal time scale-based framework for soft glassy materials, where inhomogeneous flows characterized by shear bands and/or pluglike flow play a central role.
The stress-induced yielding scenario of colloidal gels is investigated under rough boundary conditions by means of rheometry coupled with local velocity measurements. Under an applied shear stress σ, the fluidization of gels made of attractive carbon black particles dispersed in a mineral oil is shown to involve a previously unreported shear rate response γ dot above(t) characterized by two well-defined and separated timescales τc and τf. First γ dot above decreases as a weak power law strongly reminiscent of the primary creep observed in numerous crystalline and amorphous solids, coined the "Andrade creep". We show that the bulk deformation remains homogeneous at the micron scale, which demonstrates that whether plastic events take place or whether any shear transformation zone exists, such phenomena occur at a smaller scale. As a key result of this paper, the duration τc of this creep regime decreases as a power law of the viscous stress, defined as the difference between the applied stress and the yield stress σc, i.e. τc ∼ (σ - σc)(-β), with β = 2-3 depending on the gel concentration. The end of this first regime is marked by a jump of the shear rate by several orders of magnitude, while the gel slowly slides as a solid block experiencing strong wall slip at both walls, despite rough boundary conditions. Finally, a second sudden increase of the shear rate is concomitant with the full fluidization of the material which ends up being homogeneously sheared. The corresponding fluidization time τf robustly follows an exponential decay with the applied shear stress, i.e. τf = τ0 exp(-σ/σ0), as already reported for smooth boundary conditions. Varying the gel concentration C in a systematic fashion shows that the parameter σ0 and the yield stress σc exhibit similar power-law dependences with C. Finally, we highlight a few features that are common to attractive colloidal gels and to solid materials by discussing our results in the framework of theoretical approaches of solid rupture (kinetic, fiber bundle, and transient network models).
We describe a technique coupling standard rheology and ultrasonic imaging with promising applications to characterization of soft materials under shear. Plane wave imaging using an ultrafast scanner allows to follow the local dynamics of fluids sheared between two concentric cylinders with frame rates as high as 10 000 images per second, while simultaneously monitoring the shear rate, shear stress, and viscosity as a function of time. The capacities of this "rheo-ultrasound" instrument are illustrated on two examples: (i) the classical case of the Taylor-Couette instability in a simple viscous fluid and (ii) the unstable shear-banded flow of a non-Newtonian wormlike micellar solution.
In the past twenty years, shear-banding flows have been probed by various techniques, such as rheometry, velocimetry and flow birefringence. In micellar solutions, many of the data collected exhibit unexplained spatiotemporal fluctuations. Recently, it has been suggested that those fluctuations originate from a purely elastic instability of the shear-banding flow. In cylindrical Couette geometry, the instability is reminiscent of the Taylor-like instability observed in viscoelastic polymer solutions. The criterion for purely elastic Taylor-Couette instability adapted to shear-banding flows suggested three categories of shear-banding depending on their stability. In the present study, we report on a large set of experimental data which demonstrates the existence of the three categories of shear-banding flows in various surfactant solutions. Consistent with theoretical predictions, increases in the surfactant concentration or in the curvature of the geometry destabilize the flow, whereas an increase in temperature stabilizes the flow. But experiments also exhibit some interesting behaviors going beyond the purely elastic instability criterion.
Various dispersions of attractive particles are known to aggregate into patterns of vorticity-aligned stripes when sheared in confined geometries. We report a thorough experimental investigation of such shear-induced vorticity alignment through direct visualization of carbon black gels in both simple plane shear and rotational shear cells. Control parameters such as the gap width, the strain rate, and the gel concentration are systematically varied. It is shown that in steady states the wavelength of the striped pattern depends linearly on the gap width h while being insensitive to both the gel concentration C and the shear rateγ. The width of the vorticity-aligned flocs coincides with the gap width and is also independent of C andγ, which hints to a simple picture in terms of compressible cylindrical flocs. Finally, we show that there exists a critical shear rateγc above which structuration does not occur and thatγc scales as h −α with α = 1.4 ± 0.1 independently of C. This extensive data set should open the way to quantitative modelling of the vorticity alignment phenomenon in attractive colloidal systems.
Dilute suspensions of repulsive particles exhibit a Newtonian response to flow that can be accurately predicted by the particle volume fraction and the viscosity of the suspending fluid. However, such a description fails when the particles are weakly attractive. In a simple shear flow, suspensions of attractive particles exhibit complex, anisotropic microstructures and flow instabilities that are poorly understood and plague industrial processes. One such phenomenon, the formation of log-rolling flocs, which is ubiquitously observed in suspensions of attractive particles that are sheared while confined between parallel plates, is an exemplar of this phenomenology. Combining experiments and discrete element simulations, we demonstrate that this shear-induced structuring is driven by hydrodynamic coupling between the flocs and the confining boundaries. Clusters of particles trigger the formation of viscous eddies that are spaced periodically and whose centers act as stable regions where particles aggregate to form flocs spanning the vorticity direction. Simulation results for the wavelength of the periodic pattern of stripes formed by the logs and for the log diameter are in quantitative agreement with experimental observations on both colloidal and noncolloidal suspensions. Numerical and experimental results are successfully combined by means of rescaling in terms of a Mason number that describes the strength of the shear flow relative to the rupture force between contacting particles in the flocs. The introduction of this dimensionless group leads to a universal stability diagram for the log-rolling structures and allows for application of shear-induced structuring as a tool for assembling and patterning suspensions of attractive particles.
We report on measurements of the transverse fluctuations of a string in a turbulent air jet flow. Harmonic modes are excited by the fluctuating drag force, at different wave-numbers. This simple mechanical probe makes it possible to measure excitations of the flow at specific scales, averaged over space and time: it is a scale-resolved, global measurement. We also measure the dissipation associated to the string motion, and we consider the ratio of the fluctuations over dissipation (FDR). In an exploratory approach, we investigate the concept of effective temperature defined through the FDR. We compare our observations with other definitions of temperature in turbulence. From the theory of Kolmogorov (1941), we derive the exponent −11/3 expected for the spectrum of the fluctuations. This simple model and our experimental results are in good agreement, over the range of wave-numbers, and Reynolds number accessible (74000 ≤ Re ≤ 170000).
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