Coal is a major contributor to power and heat generation in the United
States. According to
economic forecasts coal mining and consumption as fuel will increase
through 2010. Simultaneously, deposits of ash from coal combustion are expected to accumulate
extensively. Today,
about quarter of coal combustion solid waste is used for cement and
concrete production. Many
millions of tons of aluminum and silicon contained in the coal wastes
are annually lost in landfills.
Use of coal ash as a raw material for production of chemicals and
construction materials can
significantly fulfill the U.S. need for these commodities while at the
same time decrease dusty
pollution. A fairly large number of processes for recovering
alumina and byproducts from coal
ash have been proposed and developed. These processes are
classified by methods of ash
decomposition into sintering and hydrothermal technologies and by
extractant type into alkaline
and acidic groups. On the basis of the available calculations,
preference should be given to a
combined process including the alkaline pre-extraction of silicon
followed by lime−soda sintering
of desilicated solid remainder. This review covers 98 papers,
patents, and reports issued over
the last 30 years. U.S. chemical and metallurgical industries are
expected to resume growing
through the end of the decade, and coal ash should be recognized as a
practicable domestic raw
material which can be utilized in a number of ways.
Deposits of bauxite ores near aluminum smelters often possess an excessively high percentage of silica. Development of such high-silica ores would be benefi cial to alumina producers. Therefore, unique industrial and operational experience in the fi eld of high-silica bauxite processing was gained at the R u s s i a n N a t i o n a l A l u m i n i u m -Magnesium Institute, St. Petersburg, pilot plant with the consecutive extraction of silica and alumina from low-grade ores. This article describes the chemistry, processing-unit operations, and results obtained from this process.
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