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A functionalised coating for mild steel corrosion protection was prepared in this study. A composite material SBA-15 (silicon oxide) was used as a mild steel corrosion inhibitor. The porous matrix (SBA-15) was loaded with fluconazole (F), as an inhibitor container. A sol-gel technique was used to synthesise SBA-15; and the active molecule (F) was extracted from an outdated medication using methanol as solvent. The final composite was obtained by SO 2 dispersion in a methanol-F solution. The composite material was dispersed in a nitrocellulose resin, and it was characterised by X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Transmission Electron Microscope (TEM), Fourier Transform Infrared Spectrometry (FTIR), and physical adsorption of Nitrogen. Coatings were electrochemically evaluated by electrochemical impedance spectroscopy (EIS) tests, using a chloride/sulphate solution prepared from NaCl and (NH 4 ) 2 SO 4 . The results demonstrated the effectiveness of the inhibitor delivery system and the consequent protection of metal against the corrosion process.

The biodegradation of domestic wastewater contaminants has been carried out using microorganisms immobilized in sodium alginate gel (Alg‐Na). A fixed bed reactor with immobilized microorganisms was used for the treatment of domestic wastewater. A wastewater pretreatment was carried out to remove the larger particulate matter, which consisted of a reactor packed with different materials (anthracite, zeolite, and activated carbon). Later, a second reactor packed with balls with immobilized microorganisms was used to eliminate organic matter and nutrients. 2.5% w/v of Alg‐Na was used as a support to immobilize the microorganisms. According to the results, a total phosphorus (TP) and chemical oxygen demand (COD) removal of 94.26% and 78.25% was obtained, respectively. In addition, the degradation rate for both organic matter and phosphorous was studied by using the kinetic model for fix bed reactor. © 2020 Water Environment Federation Practitioner points Phosphorous and organic matter removal by adsorption and immobilized microorganisms. High removal efficiency of phosphorous and organic matter was found. An innovative wastewater treatment alternative is proposed. Kinetic model for fixed bed reactor is also proposed for scaling‐up purposes.

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In this study, the use of Polyvinylchloride (PVC) and High Density Polystyrene (HDPS) was demonstrated as an alternative for the adsorption of Malathion. Adsorption kinetics and isotherms were used to compare three different adsorbent materials: PVC, HDPS, and activated carbon. The adsorption capacity of PVC was three times higher than activated carbon, and a theoretical value of 96.15 mg of Malathion could be adsorbed when using only 1 g of PVC. A pseudo first-order rate constant of 1.98 (1/h) was achieved according to Lagergren kinetic model. The adsorption rate and capacity values obtained in the present study are very promising since with very little adsorbent material it is possible to obtain high removal efficiencies. Phosphorous and sulfur elements were identified through Energy Dispersive X-ray (EDX) analysis and evidenced the malathion adsorption on PVC. The characteristic spectrum of malathion was identified by the Fourier Transform Infrared (FTIR) Spectroscopy analysis. The Thermogravimetric and Differential Thermal Analysis (TG/DTA) suggested that the adsorption of malathion on the surface of the polymers was mainly determined by hydrogen bonds.

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Currently there is a growing concern about the presence of emerging contaminants (EC) in water bodies and their potential ecotoxicological effects. Pharmaceuticals, a type of EC, are widely distributed in the environment and their main entry is through wastewater from treatment plants, since these systems are not designed to remove EC. In this sense, the photo-Fenton process, an advanced oxidation process, has proven to be highly efficient in degrading new potentially harmful contaminants. However, this process is affected by multiple factors, which makes it necessary to implement a methodological strategy to optimize the photo-Fenton process. Within these, the Taguchi method provides robust and low-cost solutions with the least number of experiments, providing knowledge of the contribution of each of the factors studied to the response variable. In addition to the above, the Taguchi method can be coupled to a Grey relational analysis (Grey–Taguchi method), which will allow the optimization of more than one response variable at the same time. This paper discusses the parameters that affect the photo-Fenton process and the application of designs of experiments to optimize the process.