Exploiting the properties of two-dimensional crystals requires a mass production method able to produce heterostructures of arbitrary complexity on any substrate. Solution processing of graphene allows simple and low-cost techniques such as inkjet printing to be used for device fabrication. However, the available printable formulations are still far from ideal as they are either based on toxic solvents, have low concentration, or require time-consuming and expensive processing. In addition, none is suitable for thin-film heterostructure fabrication due to the re-mixing of different two-dimensional crystals leading to uncontrolled interfaces and poor device performance. Here, we show a general approach to achieve inkjet-printable, water-based, two-dimensional crystal formulations, which also provide optimal film formation for multi-stack fabrication. We show examples of all-inkjet-printed heterostructures, such as large-area arrays of photosensors on plastic and paper and programmable logic memory devices. Finally, in vitro dose-escalation cytotoxicity assays confirm the biocompatibility of the inks, extending their possible use to biomedical applications.

The present work describes the inkjet printing and low temperature sintering of silver nanoparticle inks onto transfer tattoo paper. Our approach results in silver features of excellent resolution and conductivity and, subsequently the first passive UHF RFID transfer tattoo tags functional mounted on human skin of improved performance when compared to screen printed passive UHF RFID transfer tattoo paper tags.Moreover, inkjet printed passive UHF RFID transfer tattoo tags show similar performance to copper etched passive UHF RFID tags on plastic substrates. This study compares the image quality (resolution) and electrical performance of two commercial silver nanoparticle inks inkjet printed on transfer tattoo paper.The optimal printing and sintering parameters to obtain high resolution features of resistivities 20 to 57 times the resistivity of bulk silver (1.59 Â 10 À6 ohm cm) are described. We demonstrate how, by selectively depositing ink in specific areas of the antenna, read distance of passive UHF RFID tags can be increased from 54 to 68 cm whilst decreasing the amount of ink used by 33%. Furthermore, this approach results in inkjet printed passive UHF RFID tattoo tags with larger read distance than silver screen printed passive UHF RFID tattoo tags, 45 cm, and similar to copper etched passive UHF RFID plastic tags, 75 cm. Moreover, inkjet printed passive UHF RFID tattoo tags in this work are considerably thinner (1-5 mm) than screen and etched passive UHF RFID tags (tens of micrometers) hence, making the former more appealing to the end user. In addition to this, inkjet printing is compatible with large area manufacturing techniques and has the potential to evolve as one of the most promising RFID mass-production techniques. Therefore, this work represents a step towards the commercialization of on-body transfer tattoo paper passive UHF RFID tags.

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Interdependence between ink, substrate and sintering method on inkjet printed devices.

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As a step towards low cost manufacture of conducting arrays for Frequency Selective Surfaces an inkjet procedure is under development. The plane wave transmission response of a printed array compares well with its conventionally etched counterpart and the predictions of modelling software.

Additive fabrication of electromagnetic structures by inkjet printing technology is both cost effective and compatible with a wide range of environmentally friendly substrates, enabling the fabrication of frequency-selective surface (FSS) arrays with line dimensions less than 0.1 mm, which is difficult to achieve with conventional subtractive techniques. Several approaches, such as savings in ink by depositing it at the edges of dipole elements where the surface current tends to maximize, have been investigated in order to produce low-cost frequencyselective panels with acceptable level of isolation. The FSS transmission characteristics were improved by jetting multiple ink layers on the whole elements and at the edges. The electrical resistance of various arrays have been measured and analyzed and has been used to assess the performances of the FSS.

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