We report the broadband nonlinear optical (NLO) properties of CsPbBr perovskite films achieved from colloidal nanocrystals prepared following a room temperature and open atmosphere anti-solvent precipitation method. The NLO studies were performed on the films of nanocubes (NCs) and nanorods (NRs) using the Z-scan technique with 1 kHz femtosecond pulses at 600, 700, and 800 nm. Large two-photon absorption cross sections (∼10 GM) were retrieved by fitting the open-aperture Z-scan data. Strong third-order NLO susceptibility (∼10 esu) was observed in these films. At higher peak intensities a switching of sign (in both NCs and NRs) in the real and imaginary parts of the NLO susceptibility was observed from the studies on these CsPbBr nanocrystals. The obtained NLO coefficients clearly suggest that these materials are promising for ultrafast photonic applications.
While the unabated race persists in achieving record efficiencies in solar cells and other photonic/optoelectronic devices using lead halide perovskite absorbers, a comprehensive picture of the correlated third-order nonlinear optical (NLO) properties is yet to be established. The present study is aimed at deciphering the role of dopants in multiphoton absorption properties of intentionally engineered CsPbBr 3 colloidal nanocrystals (NCs). The charge separation of the plasmonsemiconductor conduction band owing to the hot electron transfer at the interface was demystified using the dynamics of the bleached spectral data from femtosecond (fs) transient absorption spectroscopy with broadband capabilities. The NLO properties studied through the fs Z-scan technique revealed that Ni-doped CsPbBr 3 NCs exhibited strong third-order NLO susceptibility of ∼10 −10 esu. The exotic photophysical phenomena in these pristine and Ni-doped CsPbBr 3 colloidal twodimensional (2D) NCs reported herein are believed to provide the avenues to address the critical variables involved in the structural differences and their correlated optoelectronic properties.
We present a systematic study on
the fabrication, characterization
of versatile, and low-cost filter paper-based surface-enhanced Raman
spectroscopy (SERS) substrates loaded with salt-induced aggregated
Ag/Au nanoparticles (NPs). These were demonstrated as efficient SERS
substrates for the detection of multiple explosive molecules such
as picric acid (5 μM), 2,4-dinitrotoluene (1 μM), and
3-nitro-1,2,4-triazol-5-one (10 μM) along with a common dye
molecule (methylene blue, 5 nM). The concentrations of the dye and
explosive molecules in terms of mass represent 31.98 pg, 11.45 ng,
1.82 ng, and 13.06 ng, respectively. Silver (Ag) and gold (Au) colloidal
NPs were prepared by femtosecond laser (∼50 fs, 800 nm, 1 kHz)
ablation of Ag/Au-target immersed in distilled water. Subsequently,
the aggregated nanoparticles were achieved by mixing the pure Ag and
Au NPs with different concentrations of NaCl. These aggregated NPs
were characterized by UV–visible absorption and high-resolution
transmission electron microscopy techniques. The SERS substrates were
prepared by soaking the filter paper in aggregated NPs. The morphologies
of the paper substrates were investigated using field-emission scanning
electron microscopy technique. We have achieved superior enhancements
with high reproducibility and sensitivity for filter paper substrates
loaded with Ag/Au NPs mixed for an optimum concentration of 50 mM
NaCl.
This article reviews the most recent advances in the development of flexible substrates used as surface-enhanced Raman scattering (SERS) platforms for detecting several hazardous materials (e.g., explosives, pesticides, drugs, and dyes). Different flexible platforms such as papers/filter papers, fabrics, polymer nanofibers, and cellulose fibers have been investigated over the last few years and their SERS efficacies have been evaluated. We start with an introduction of the importance of hazardous materials trace detection followed by a summary of different SERS methodologies with particular attention on flexible substrates and their advantages over the nanostructures and nanoparticle-based solid/hybrid substrates. The potential of flexible SERS substrates, in conjunction with a simple portable Raman spectrometer, is the power to enable practical/on-field/point of interest applications primarily because of their low-cost and easy sampling.
In this paper, we
present results from the detailed investigations
on the synthesis, optical, emission, electrochemical, and ultrafast
nonlinear optical (NLO) properties along with the excited state dynamics
of zinc(II) 2,10,16,24-tetrakis(9-phenyl-9H-carbazol-2-yl)phthalocyanine
(CBZPC1) and zinc(II) 2,10,16,24-tetrakis(4-(9H-carbazol-9-yl)phenyl)phthalocyanine (CBZPC2). Due to the presence of carbazole moieties, the Soret band was
found to be broadened. The emission studies performed using different
solvents revealed the fluorescence yields in the range of 0.10–0.27
and the time-resolved fluorescence data revealed radiative lifetimes
of, typically, a few nanoseconds. Femtosecond transient absorption
measurements indicated the formation of triplet states within the
first nanosecond of photoexcitation. From the cyclic voltametric studies,
the oxidation and reduction processes were found to be ring centered.
Spectral changes in the UV–visible absorption were recorded
by means of spectro-electrochemical analysis at an applied potential.
The DFT and TD-DFT analysis was employed using B3LYP hybrid functional
theory and 6-31G(d,p) basis set in the Gaussian 09 package. The NLO
properties of CBZPC1 and CBZPC2 were investigated
using the Z-scan technique and femtosecond (fs) pulses
with kHz and MHz repetition rates. Closed and open aperture Z-scan data were recorded at three different wavelengths
of 600, 700, and 800 nm, and the NLO coefficients were extracted from
both types of data. Two-photon absorption (TPA) was the dominant mechanism
observed in the open aperture Z-scan data. The real
and imaginary parts of the χ(3) along with the two-photon
absorption cross sections were evaluated. Our NLO data and large 2PA
coefficients and cross sections obtained indicate the potential of
these compounds for applications in optical limiting and optical switching
applications.
Ultrafast laser pulses induced surface nanostructures were fabricated on a copper (Cu) target through ablation in acetone, dichloromethane, acetonitrile, and chloroform. Surface morphological information accomplished from the field emission scanning electron microscopic data demonstrated the diversities of ablation mechanism in each case. Fabricated Cu substrates were utilized exultantly to investigate the surface plasmon (localized and propagating) mediated enhancements of different analytes using surface enhance Raman scattering (SERS) studies. Multiple utility of these substrates were efficiently demonstrated by collecting the SERS data of Rhodamine 6G molecule and two different secondary explosive molecules such as 5-amino-3-nitro-l,2,4-triazole and trinitrotoluene on different days which were weeks apart. We achieved significant enhancement factors of >105 through an easily adoptable cleaning procedure.
Surface enhanced Raman spectroscopy (SERS) is a cutting edge analytical tool for trace analyte detection due to its highly sensitive, non-destructive and fingerprinting capability.
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