Rational design and construction of the finest electrocatalytic materials are important for improving the performance of electrochemical sensors. Spinel bioxides based on cobalt manganate (CoMn 2 O 4 ) are of particular importance for electrochemical sensors due to their excellent catalytic performance. In this study, three-dimensional CoMn 2 O 4 with the petal-free, flowerlike structure is synthesized by facile hydrothermal and calcination methods for the electrochemical sensing of roxarsone (RXS). The effect of calcination temperature on the characteristics of CoMn 2 O 4 was thoroughly studied by in-depth electron microscopic, spectroscopic, and analytical methods. Compared to previous reports, CoMn 2 O 4 -modified screen-printed carbon electrodes display superior performance for the RXS detection, including a wide linear range (0.01−0.84 μM; 0.84−1130 μM), a low limit of detection (0.002 μM), and a high sensitivity (33.13 μA μM −1 cm −2 ). The remarkable electrocatalytic performance can be attributed to its excellent physical properties, such as good conductivity, hybrid architectures, high specific surface area, and rapid electron transportation. More significantly, the proposed electrochemical sensor presents excellent selectivity, good stability, and high reproducibility. Besides, the detection of RXS in river water samples using the CoMn 2 O 4 -based electrochemical sensor shows satisfactory recovery values in the range of 98.00−99.80%. This work opens a new strategy to design an electrocatalyst with the hybrid architecture for high-performance electrochemical sensing.
Magnesium is one of the lightest structural metals have the capability to replace the conventional alloys for mass saving applications and provides higher strength and stiffness. Additionally, it also has the ability to absorb the hydrogen in the form of hydrides and can be used as a future source of energy carrier. The theoretical hydrogen capacity of 7.6 wt% makes it more suitable for future energy sources but needs to reduce the working sorption temperature. Moreover, magnesium is the primary source of the body and has strength equal to the bone, making it more suitable for biomedical applications and higher biocompatibility. Some challenges of magnesium-based metal matrix composites are still encountering structural applications, hydrogen energy storage, and biomedical applications due to manufacturing methodologies and proper materials selection to get required results.
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