Multiferroic behavior in perovskite-related metal-organic frameworks of general formula [(CH(3))(2)NH(2)]M(HCOO)(3), where M = Mn, Fe, Co, and Ni, is reported. All four compounds exhibit paraelectric-antiferroelectric phase transition behavior in the temperature range 160-185 K (Mn: 185 K, Fe: 160 K; Co: 165 K; Ni: 180 K); this is associated with an order-disorder transition involving the hydrogen bonded dimethylammonium cations. On further cooling, the compounds become canted weak ferromagnets below 40 K. This research opens up a new class of multiferroics in which the electrical ordering is achieved by means of hydrogen bonding.

Cyclic alkyl(amino) carbene stabilized two- and three-coordinate Fe(I) complexes, (cAAC)2FeCl (2) and [(cAAC)2Fe][B(C6F5)4] (3), respectively, were prepared and thoroughly studied by a bouquet of analytical techniques as well as theoretical calculations. Magnetic susceptibility and Mössbauer spectroscopy reveal the +1 oxidation state and S = 3/2 spin ground state of iron in both compounds. 2 and 3 show slow magnetic relaxation typical for single molecule magnets under an applied direct current magnetic field. The high-frequency EPR measurements confirm the S = 3/2 ground state with a large, positive zero-field splitting (∼20.4 cm(-1)) and reveal easy plane anisotropy for compound 2. CASSCF/CASPT2/RASSI-SO ab initio calculations using the MOLCAS program package support the experimental results.

Aerobic oxidation that incorporates both O atoms into a substrate (PPh(3)) is achieved by employing a Cr(III)/Cr(V)[triple bond]O catalytic couple. A terphenyl trianionic pincer ligand stabilizes a high oxidation state Cr(V)[triple bond]O complex, and both the reduced (Cr(III), IR/X-ray) and oxidized (Cr(V)[triple bond]O, electron paramagnetic resonance/IR/X-ray) participants in the catalytic cycle are characterized.

Monodisperse, water-soluble dextran-coated iron oxide (Fe 3 O 4 ) nanorods were synthesized using a facile and scalable approach. Our room temperature method involves the mixing of an acidic solution of iron salts with a basic solution of ammonium hydroxide to facilitate initial formation of iron oxide crystals. The stability, crystalinity and shape of these nanorods depends on the time of addition of the dextran, as well as the degree of purity of the polymer. The as-synthesized nanorods exhibit unique magnetic properties, including superparamagnetic behavior and high spin-spin water relaxivity (R2). Additionally, they possess enhanced peroxidase activity when compared to those reported in the literature for spherical iron oxide nanoparticles. Thus, this high yield synthetic method for polymer-coated iron oxide nanorods will expedite their use in applications from magnetic sensors, devices and nanocomposites with magnetic and catalytic properties.

Two discrete anionic palladium(II)-oxo clusters have been prepared: [Pd(13)(As(V)Ph)(8)O(32)](6-) (1) and [Pd(13)Se(IV)(8)O(32)](6-) (2) were synthesized in one-pot self-assembly reactions of Pd(OAc)(2) with PhAsO(3)H(2) and SeO(2) and characterized by single-crystal X-ray analysis, IR, thermogravimetric analysis, elemental analysis, magnetic and electron paramagnetic resonance measurements, and electrochemistry.

To check on the nature of the weak magnetic order in polycrystalline magnetoelectric Pb(Fe1∕2Nb1∕2)O3 the X-band, Q-band, and far infrared electron paramagnetic resonance (EPR) spectra have been measured between 4 and 600K and compared with magnetic susceptibility and magnetization data. The asymmetric line shapes can be simulated at higher temperature by thermally fluctuating superparamagnetic nanoclusters. The pronounced temperature dependence of the position of the spectra demonstrates the presence of an internal magnetic field which is small but nonzero even at room temperature, i.e., far above the antiferromagnetic transition. The electronic spin-spin exchange has been found to be in the terahertz range. The magnetization data reveal a weak ferromagnetism even above 300K and a break in the temperature dependence of susceptibility at the paramagnetic to ferromagnetic transition.

A series of novel yttrium- and lanthanide-containing heteropolyoxopalladates have been prepared and isolated as hydrated sodium salts, Na(5)[X(III)Pd(II)(12)(AsPh)(8)O(32)]y H(2)O (X=Y (1), Pr (2), Nd (3), Sm (4), Eu (5), Gd (6), Tb (7), Dy (8), Ho (9), Er (10), Tm (11), Yb (12), Lu (13); y=15-27). The polyanions [X(III)Pd(II)(12)(AsPh)(8)O(32)](5-) consist of a cuboid framework of twelve Pd(II) ions with eight phenylarsonate heterogroups located at the vertices and a central guest ion X. The compounds 1-13 have been prepared in a simple one-pot self-assembly reaction of Pd(CH(3)COO)(2), phenylarsonic acid and the respective salt of the element X in 0.5 M aqueous sodium acetate solution (pH 6.9), and characterized in the solid state by single-crystal X-ray diffraction, elemental and thermogravimetric (TGA) analyses, and IR spectroscopy. It was demonstrated that small, medium, and also large lanthanide ions can be incorporated in the center of the novel heteropolypalladate [X(III)Pd(II)(12)(AsPh)(8)O(32)](5-). The Ln-O bond lengths follow the expected trend decreasing from left to right in the lanthanide series. This indicates that the {Pd(II)(12)O(32)} shell can adjust to the coordination requirements of the encapsulated guest cation. Compounds 3 and 5 were selected for electrochemical studies. Their cyclic voltammetry in a lithium acetate buffer at pH 5.9 showed a Pd(0) deposition process on the glassy carbon electrode surface. Coulometry indicated that all Pd(II) centers were reduced to Pd(0). The film was stable and could be taken out of the deposition medium and characterized in pure pH 5.9 buffer. Magnetic susceptibility and EPR measurements were carried out on 5 and 6. The former was confirmed to be diamagnetic and the latter strongly paramagnetic with a S=7/2 ground state. DFT calculations for some of the polyoxometalates have been also performed.

Synthetic and kinetic experiments designed to probe the mechanism of O(2) activation by the trianionic pincer chromium(III) complex [(t)BuOCO]Cr(III)(THF)(3) (1) (where (t)BuOCO = [2,6-((t)BuC(6)H(3)O)(2)C(6)H(3)](3-), THF = tetrahydrofuran) are described. Whereas analogous porphyrin and corrole oxidation catalysts can become inactive toward O(2) activation upon dimerization (forming a μ-oxo species) or product inhibition, complex 1 becomes more active toward O(2) activation when dimerized. The product from O(2) activation, [(t)BuOCO]Cr(V)(O)(THF) (2), catalyzes the oxidation of 1 via formation of the μ-O dimer {[(t)BuOCO]Cr(IV)(THF)}(2)(μ-O) (3). Complex 3 exists in equilibrium with 1 and 2 and thus could not be isolated in pure form. However, single crystals of 3 and 1 co-deposit, and the molecular stucture of 3 was determined using single-crystal X-ray crystallography methods. Variable (9.5, 35, and 240 GHz) frequency electron paramagnetic resonance spectroscopy supports the assignment of complex 3 as a Cr(IV)-O-Cr(IV) dimer, with a high (S = 2) spin ground state, based on detailed computer simulations. Complex 3 is the first conclusively assigned example of a complex containing a Cr(IV) dimer; its spin Hamiltonian parameters are g(iso) = 1.976, D = 2400 G, and E = 750 G. The reaction of 1 with O(2) was monitored by UV-visible spectrophotometry, and the kinetic orders of the reagents were determined. The reaction does not exhibit first-order behavior with respect to the concentrations of complex 1 and O(2). Altering the THF concentration reveals an inverse order behavior in THF. A proposed autocatalytic mechanism, with 3 as the key intermediate, was employed in numerical simulations of concentration versus time decay plots, and the individual rate constants were calculated. The simulations agree well with the experimental observations. The acceleration is not unique to 2; for example, the presence of OPPh(3) accelerates O(2) activation by forming the five-coordinate complex trans-[(t)BuOCO]Cr(III)(OPPh(3))(2) (4).