This study deals with the deagglomeration of nanoparticles in low concentration suspensions in water, protic polar solvent for polymers such as poly(vinyl alcohol) (PVA). The influence of the main parameters of ultrasonication such as time, power and irradiation modes (continuous, pulsed) on the cluster size of aluminium oxide nanoparticles 1 mg/ml in aqueous solutions was investigated. Power-law dependence of size reduction on ultrasonic time was observed. The study indicated an optimum power input, i.e. at higher vibration amplitude the break up of nanoparticle clusters was no better and there was a risk of reagglomeration occurring during a long ultrasonication. Under optimal conditions, continuous and pulsed irradiations showed almost the same efficiency of deagglomeration over a given time. This result provides alternative operating conditions for attaining the smallest size of the alumina aggregates in suspension. The influence of stabilization on the cluster size was also studied. Alumina nanoparticles were stabilized by electrostatic forces against reagglomeration without the need for dispersants, and the enhancement of dispersion stability using electrostatic, steric effects had no significant effect on the aggregate size. On the contrary, the adsorption of high molecular weight polyelectrolytes onto the particle surface could lead to reagglomeration due to material bridges between particle surfaces and even flocculation.
Hybrid nanocomposites based on crystalline nanoparticles dispersed in polymer matrix have been widely studied in the past few years because of the ability of these materials to combine the properties of organic polymer and inorganic nanoparticles. The aim of this work is to tune the mechanical properties of a piezoelectric polymer by adding nanoparticles to the matrix. In this paper, alumina nanoparticles were dispersed in the copolymer P(VDF-TrFE), which exhibits high piezoelectric coefficient after polarization under high electric field without needing stretching during the polarization process. Transmission electron microscopy and scanning electron microscopy demonstrate the high rate of welldispersed nanoparticles with 10% of alumina nanoparticles added to the matrix. Piezoelectric measurements indicate that P(VDF-TrFE) may be filled by up to 10 wt% of alumina while retaining its high piezoelectric properties and increasing its elastic constant by more than 20%, measured by Brillouin spectroscopy. This work opens a wide range of applications using nanoparticles with nonlinear optical, pyroelectric, magnetic, or ferroelectric properties.
Silicon nitride and silicon oxynitride films with refractive indices varying from 1.60 to 1.95 were deposited on silicon substrates using plasma‐enhanced chemical vapor deposition (PECVD) processing. Variation of the film's physical properties with composition is examined. Refractive indices, infrared, Auger analysis, and plasma etching of plasma‐deposited films are studied before and after an annealing cycle. A direct correlation between etch rates and etch profiles of the deposited films with their composition was observed. Plasma etching, using a
92%CF4+8%O2
gas mixture, showed that the etch rate of oxynitride film increases with hydrogen concentration and decreases as the oxygen content increases. The length of the undercut, i.e., etch profile, depends on the amount of oxygen and hydrogen content in the films. Infrared data suggests that silicon oxynitride film with a refractive index of 1.75 is more stable under thermal annealing cycles, as compared to other silicon oxynitride films. Ellipsometric measurements showed that film thickness and refractive index uniformity are comparable with those of CVD processing. However, Auger depth profile analysis revealed poor compositional uniformity in all deposited films, especially at the silicon or silicon dioxide substrate interfaces.
The initial transient phenomenon in plasma processing, an intrinsic and unstable phenomenon of the glow discharge, is found to be the probable cause of the hydrogen‐poor and silicon‐rich structure and the silicon nitride(or oxynitride)‐silicon substrate interfaces of all plasma‐deposited films. A simple and qualitative model was developed to explain the variation of the interface composition of the film with this transient phenomenon. Fourier transform infrared and electron spin resonance measurements suggest the existence of a “stable” amorphous silicon oxynitride
false(RI≃1.75false)
composition in films prepared by plasma‐enhanced chemical vapor deposition processing.
International audiencePiezoelectric films were prepared by incorporation of lithium niobate (LiNbO3) nanoparticles into copolymer of vinylidene difluoride and trifluoroethylene. Nanoparticles of LiNbO3 with ferroelectric phase were successfully synthesized and dispersed homogenously by ultrasonication in the copolymer matrix without any surfactant or surface functionalization. The nanocomposites were fully characterized by electronic microscopy, X-ray diffraction, differential scanning calorimetry, dynamical mechanical analysis, and piezometer. Surprisingly, the copolymer matrix crystallinity and morphology were not affected by the incorporation of nanoparticles. Therefore the nanocomposites remained good mechanicals properties and high ferroelectricity coupled to nonlinear optical activity thanks to the noncentro symmetric space group of lithium niobate. This could be a novel approach to develop new multifunctional materials
This work is devoted to a systematic study of nanoparticle dispersion by ultrasonication in different solutions: from organic solvents to polymer solutions. The cluster size of nanoparticles at different concentrations in both organic solvents and polymer solutions were directly characterized by Dynamic Light Scattering to study the effect of solid concentration, surfactant and polymer on the dispersion. It reveals that in stabilized suspensions, the smallest attainable size or aggregate size of nanoparticles is independent of solvent type and solid content over the tested range. Furthermore, nanoparticles in simple solvent and in polymer solutions had the similar evolution of cluster size and almost the same final size, which could be very helpful to optimize the dispersion of nanofillers in polymer solutions and nanocomposites. It is also shown that, with appropriate sonication amplitudes, the dispersion procedure developed for very dilute suspensions could be transferred to higher concentration suspensions or even to polymer suspensions.
Lithium cobalt oxide nanobatteries offer exciting prospects in the field of nonvolatile memories and neuromorphic circuits. However, the precise underlying resistive switching (RS) mechanism remains a matter of debate in two-terminal cells. Herein, intriguing results, obtained by secondary ion mass spectroscopy (SIMS) 3D imaging, clearly demonstrate that the RS mechanism corresponds to lithium migration toward the outside of the Li CoO layer. These observations are very well correlated with the observed insulator-to-metal transition of the oxide. Besides, smaller device area experimentally yields much faster switching kinetics, which is qualitatively well accounted for by a simple numerical simulation. Write/erase endurance is also highly improved with downscaling - much further than the present cycling life of usual lithium-ion batteries. Hence very attractive possibilities can be envisaged for this class of materials in nanoelectronics.
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