A mono-dimensional code for the simulation of the effects of High Frequency Ignition systems (HFI) on the production of chemical radicals was developed and here presented. The simulations were carried out by considering the typical environmental thermodynamic conditions of a nowadays engine at full load. An electron transport model is linked with a Boltzmann solver coupled with a chemistry solver, affecting the Electron Energy Distribution Function (EEDF) in order to obtain the physical conditions leading to the production of radical components for a given fuel mixture. The transport equations for the electrons, the positive and the negative ions, and the Gauss’ law in a steady-state plasma region. Then the Boltzmann equation for the electrons, in a spatially homogeneous steady-state case, is solved in order to obtain the EEDF. Finally the chemical kinetics model is employed assuming a fuel-air mixture neglecting the fuel carbon atoms due to the assumption that electron-impact dissociation reactions, which initiate the combustion, exhibit a greater reaction rate compared to those based on hydrocarbon thermal dissociation and therefore can be neglected in this work. Results show the production of the hydrogen (H), nitrogen (N), and oxygen (O) radicals and the radius of the initial discharge under different simulated engine operating conditions characterizing the role of a plasma corona effect for the induced chemical ignition in gasoline-powered engines.
Increasingly stringent pollutant emission limits and CO2 reduction policies are forcing the automotive industry toward cleaner and decarbonized mobility. The goal is to achieve carbon neutrality within 2050 and limit global warming to 2 °C (possibly 1.5 °C) with respect to pre-industrial levels as stated in both the European Green Deal and the Paris Agreement and further reiterated at the COP26. With the aim of simultaneously reducing both pollutants and CO2 emissions, a large amount of research is currently carried out on low-temperature highly efficient combustions (LTC). Among these advanced combustions, one of the most promising is Gasoline Compression Ignition (GCI), based on the spontaneous ignition of a gasoline-like fuel. Nevertheless, despite GCI proving to be effective in reducing both pollutants and CO2 emissions, GCI combustion controllability represents the main challenge that hinders the diffusion of this methodology for transportation. Several works in the literature demonstrated that to properly control GCI combustion, a multiple injections strategy is needed. The rise of pressure and temperature generated by the spontaneous ignition of small amounts of early-injected fuel reduces the ignition delay of the following main injection, responsible for the torque production of the engine. Since the combustion of the pre-injections is chemically driven, the ignition delay might be strongly affected by a slight variation in the engine control parameters and, consequently, lead to misfire or knocking. The goal of this work was to develop a control-oriented ignition delay model suitable to improve the GCI combustion stability through the proper management of the pilot injections. After a thorough analysis of the quantities affecting the ignition delay, this quantity was modeled as a function of both a thermodynamic and a chemical–physical index. The comparison between the measured and modeled ignition delay shows an accuracy compatible with the requirements for control purposes (the average root mean squared error between the measured and estimated start of combustion is close to 1.3 deg), over a wide range of operating conditions. As a result, the presented approach proved to be appropriate for the development of a model-based feed-forward contribution for a closed-loop combustion control strategy.
Hydrogen is the energy vector that will lead us toward a more sustainable future. It could be the fuel of both fuel cells and internal combustion engines. Internal combustion engines are today the only motors characterized by high reliability, duration and specific power, and low cost per power unit. The most immediate solution for the near future could be the application of hydrogen as a fuel in modern internal combustion engines. This solution has advantages and disadvantages: specific physical, chemical and operational properties of hydrogen require attention. Hydrogen is the only fuel that could potentially produce no carbon, carbon monoxide and carbon dioxide emissions. It also allows high engine efficiency and low nitrogen oxide emissions. Hydrogen has wide flammability limits and a high flame propagation rate, which provide a stable combustion process for lean and very lean mixtures. Near the stoichiometric air–fuel ratio, hydrogen-fueled engines exhibit abnormal combustions (backfire, pre-ignition, detonation), the suppression of which has proven to be quite challenging. Pre-ignition due to hot spots in or around the spark plug can be avoided by adopting a cooled or unconventional ignition system (such as corona discharge): the latter also ensures the ignition of highly diluted hydrogen–air mixtures. It is worth noting that to correctly reproduce the hydrogen ignition and combustion processes in an ICE with the risks related to abnormal combustion, 3D CFD simulations can be of great help. It is necessary to model the injection process correctly, and then the formation of the mixture, and therefore, the combustion process. It is very complex to model hydrogen gas injection due to the high velocity of the gas in such jets. Experimental tests on hydrogen gas injection are many but never conclusive. It is necessary to have a deep knowledge of the gas injection phenomenon to correctly design the right injector for a specific engine. Furthermore, correlations are needed in the CFD code to predict the laminar flame velocity of hydrogen–air mixtures and the autoignition time. In the literature, experimental data are scarce on air–hydrogen mixtures, particularly for engine-type conditions, because they are complicated by flame instability at pressures similar to those of an engine. The flame velocity exhibits a non-monotonous behavior with respect to the equivalence ratio, increases with a higher unburnt gas temperature and decreases at high pressures. This makes it difficult to develop the correlation required for robust and predictive CFD models. In this work, the authors briefly describe the research path and the main challenges listed above.
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