Lightweight, biodegradable, thermally insulating, and electrically conductive materials play a vital role in achieving the sustainable development of our society. The fabrication of such multifunctional materials is currently very challenging. Here, we report a general, facile, and eco-friendly way for the large-scale fabrication of ultralow-threshold and biodegradable porous polylactic acid (PLA)/multiwalled carbon nanotube (MWCNT) for high-performance thermal insulation and electromagnetic interference (EMI) shielding applications. Thanks to the unique structure of the microporous PLA matrix embedded by conductive 3D MWCNT networks, the lightweight porous PLA/MWCNT with a density of 0.045 g/cm possesses a percolation threshold of 0.00094 vol %, which, to our knowledge, is the minimum value reported so far. Furthermore, the material exhibits excellent thermal insulation performance with a thermal conductivity of 27.5 mW·m·K, which is much lower than the best value of common thermal insulation materials. Moreover, it also shows outstanding EMI shielding performance characterized by its high shielding effectiveness (SE) values and absorption-dominated shielding feature. More importantly, its specific EMI SE is as high as 1010 dB·cm·g, which is superior to those of other shielding materials reported so far. Thus, this novel multifunctional material and its general fabrication methodology provide a promising way to meet the growing demand for high-performance multifunctional materials in sustainable development.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.