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The utilization of by-products and waste materials to substitute for the natural or manufactured resources is considered as a practical way to obtain green building materials. In concrete mixtures, amongst the many available options, Fly Ash (FA) as a by-product pozzolan has been used as a partial replacement of cement. As for the aggregates, lightweight agro-waste oil palm shell (OPS) can be used as a replacement to conventional aggregate for the production of lightweight aggregate concrete. The present communication aims to investigate the impact of FA on time-dependent development properties of OPS lightweight aggregate concrete, including density, water absorption, compressive strength up to 120-days, and drying shrinkage up to the age of 365-days under standard moist curing, partially early curing, and non-curing conditions. Additionally, drying shrinkage crack development was investigated. In this study, two series of concrete mixtures with different substitution levels of OPS (0%, 50%, and 100%) and FA were tested. From the obtained results, it was concluded that the incorporation of fly ash in OPS concrete reduces the density and compressive strength values. Dually, the initial and final water absorption values plus the rate of drying shrinkage at early and long-term ages increased. On top of that, a high potential of drying shrinkage crack, especially for mixtures with 100% OPS, was identified.

This paper reports a facile method for removal of sulfate from wastewater by magnetic multi-walled carbon nanotubes (MMWCNTs). Multi-walled carbon nanotubes and MMWCNTs were characterized by X-ray diffraction, Raman, transmission electron microscopy, Fourier transform infrared spectroscopy, and vibrating sample magnetometry. The results of the analysis indicated that MMWCNTs were synthesized successfully. The MMWCNTs can be easily manipulated in a magnetic field for the desired separation, leading to the removal of sulfate from wastewater. Response surface methodology (RSM) coupled with central composite design was applied to evaluate the effects of D/C (adsorbent dosage per initial concentration of pollutant (mg/(mg/l))) and pH on sulfate removal (%). Using RSM methodology, a quadratic polynomial equation was obtained, for removal of sulfate, by multiple regression analysis. The optimum combination for maximum sulfate removal of 93.28% was pH = 5.96 and D/C = 24.35. The experimental data were evaluated by the Langmuir and Freundlich adsorption models. The adsorption capacity of sulfate in the studied concentration range was 56.94 (mg/g). It was found out that the MMWCNTs could be considered as a promising adsorbent for the removal of sulfate from wastewater.

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