We developed polymer-dispersed liquid crystals (PDLCs) that effectively scatter light both in the visible and near-infrared ranges simultaneously. Such PDLCs are characterized by an optimal size distribution of nematic liquid crystal droplets within 0.4 − 3 µm, which is achieved due to the specially selected copolymer, the elaborated liquid crystal material as well as the proper cooling mode from the isotropic phase. These PDLC films provide electrically controlled light scattering modulation in the spectral range 300 − 2300 nm with the response time around 10 ms.
We report on a ferroelectric chiral smectic C (C*) phase obtained in a mixture of a nematic liquid crystal (NLC) and a chiral nonmesogenic dopant. The existence of C* phase was proven by calorimetric, dielectric and optical measurements, and also by X-rays analysis. The smectic C* which is obtained in such a way can flow, allowing to restore the ferroelectric liquid crystal layer structure in the electro-optical cells after action of the mechanical stress, as it happens with the cells filled with NLC. The proposed method of obtaining smectic C* material allows us to create innovative electro-optical cell combining the advantages of NLC (mechanical resilience) and smectic C* (high switching speed).
Antiferroelectric liquid crystals (AFLCs) with a nanoscale helix pitch (<100 nm) were revealed in a composition containing achiral smectic-C biphenylpyrimidines and two non-mesogenic chiral dopants.
Experimentally shown that the shear flow of a ferroelectric smectic C* liquid crystal (FLC) in flat capillary with homeotropic boundary conditions can be described in the framework of the Newtonian fluids theory if the pitch p 0 of the FLC helix is much less than the capillary gap. The motion of the contact line during the filling of the capillary was recorded in the experiment and compared with the theory, which made it possible to estimate the shear viscosity coefficient η 0.5 Pas, which turned out to be much larger than the rotational viscosity coefficient . In the capillary filling process, the principal optical axis of the FLC helical structure was oriented mainly perpendicular to the substrates, and the smectic layers were parallel to the substrates. At the same time, narrow dislocation bands arose along the flow direction. The principal optical axis deviated from the normal to the substrates at different angles within the dislocation bands. The total area occupied by dislocations does not exceed 5 % of the flow area; therefore, dislocations do not have a significant effect on the rheological behavior of the smectic C* phase.
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