Two series of biodegradable polymer blends were prepared from combinations of poly(L-lactide) (PLLA) with poly(e-caprolactone) (PCL) and poly(butylene succinate-co-L-lactate) (PBSL) in proportions of 100/0, 90/10, 80/ 20, and 70/30 (based on the weight percentage). Their mechanical properties were investigated and related to their morphologies. The thermal properties, Fourier transform infrared spectroscopy, and melt flow index analysis of the binary blends and virgin polymers were then evaluated. The addition of PCL and PBSL to PLLA reduced the tensile strength and Young's modulus, whereas the elongation at break and melt flow index increased. The stress-strain curve showed that the blending of PLLA with ductile PCL and PBSL improved the toughness and increased the thermal stability of the blended polymers. A morphological analysis of the PLLA and the PLLA blends revealed that all the PLLA/ PCL and PLLA/PBSL blends were immiscible with the PCL and PBSL phases finely dispersed in the PLLA-rich phase.
Plastics have become a severe risk to natural ecosystems and human health globally in the last two decades. The outbreak of the coronavirus pandemic, which led to the manufacturing and use of billions of facemasks made from non-biodegradable and petroleum-derived polymers has aggravated the situation further. There is an urgent need to develop bio-degradable facemasks with excellent filtration efficiency and antimicrobial characteristics using scalable technology. This review article aims to provide the fundamentals of mask technology, its environmental footprint, facemask’s lifecycle assessment, conventional manufacturing routes, and state-of-the-art reports on using bio-degradable polymers for facemask applications. The article also focuses on the current challenges of the conventional facemask and the prospects of an ideal facemask that could significantly reduce the ill effects of petroleum-based polymers. The review includes concise information on the basics of polymer biodegradation and standardized tests to evaluate biodegradability. The use of currently available facemasks has been an effective measure to curb the infection rate, however, is a threat to the environment. Reusing the facemask after decontamination is not a solution from a safety perspective as cloth-based facemasks have lower filtration efficiencies which get further reduced with the washing cycle necessitating a shift towards biodegradable facemask. Systematic information is provided through this article to stimulate research on a bio-degradable facemask with excellent filtration efficiency, antimicrobial properties, and cost-effectiveness for global usage.
The coronavirus pandemic (COVID-19) is currently the biggest threat to human lives due to its rapid transmission rate causing severe damage to human health and economy. The transmission of viral diseases can be minimized at its early stages with proper planning and preventive practices. The use of facemask has proved to be most effective measure to curb the spread of virus along with social distancing and good hygiene practices. This necessitates more research on facemask technology to increase its filtration efficiencies and proper disposal, which can be accelerated with knowledge of the current manufacturing process and recent research in this field. This review article provides an overview of the importance of facemask, fundamentals of nonwoven fabrics, and its manufacturing process. It also covers topics related to recent research reported for improved facemask efficiencies and testing methods to evaluate the performance of facemask. The plastic waste associated with the facemask and measures to minimize its effect are also briefly described. A systematic understanding is given in order to trigger future research in this field to ensure that we are well equipped for any future pandemic.
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