No abstract

Single-frequency operation of a 10.4-mum room-temperature multimode quantum-cascade laser was achieved by use of a 17-mm short Littrow-type external-cavity configuration. The spectral intensity of the external-cavity laser was increased as much as 20-fold compared with that of a multimode quantum-cascade laser without an external cavity. A single-frequency tuning range of 76 nm (7 cm(-1)) was achieved. The results were obtained without antireflection coating of the laser output facet.

A gas sensor for application in water analysis was developed by combination of a mid-infrared (MIR) hollow waveguide with a Fourier transform infrared (FT-IR) spectrometer and coupling of the hollow waveguide gas sensor module to a supported capillary membrane sampler (SCMS) for continuous liquid-gas extraction. Different hollow waveguides have been characterized in this study for developing an optimized optical configuration. Analysis of industrially relevant compounds has been performed, investigating chlorinated hydrocarbons (CHCs), such as dichloromethane and chloroform, representing highly volatile analytes, and 1,4-dioxane as an example of target compounds with low volatility. The suitability of this spectroscopic IR sensing system for industrial applications is demonstrated under simulated real-world conditions with limits of detection in the ppb (v/v) and ppm (v/v) concentration range for CHCs and 1,4-dioxane, respectively.