Enthalpies of addition were determined calorimetrically for the crystalline complexes MC1,.2L where M = Zr and L = pyridine or M = Mo and L = pyridine, tetrahydrofuran, or tetrahydrothiophene. Molybdenum(1V) is a significantly better acceptor than zirconium(1V) toward pyridine and tetrahydrofuran but not toward tetrahydrothiophene. A possible explanation for this is discussed.
MoCl4, das durch Erhitzen von M00, in einem CCl4‐haltigen N2‐Strom auf 300°C dargestellt wird, unterscheidet sich in seinen physikalischen Eigenschaften, besonders den magnetischen, deutlich von den bereits länger bekannten Modifikationen α‐ und β‐MOCL, (dargestellt durch Reduktion von MoCl5).
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.