Li-O2 batteries attract great attention due to their promising theoretical energy density. One of the main obstacles on the way to achieving high energy density and good cyclability is positive...

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The biogeochemical and ecological assessment of the industrial city territory including urban soils and trees was carried out. Chemical (macroelement and microelement) composition of the city soils, morphological and biochemical properties of the linden leaves, possible impact of de-icing salts on soil and tree state, the correlation between the content of trace elements, and the S-containing plant compounds (phytochelatins) were included in the assessment. It was found that concentrations of trace elements in the soils near road with intensive traffic are changed from the soils, located at a distance of 40-50 m from the road. They have higher concentrations of As, Fe, Mn, Se, and Sr and lower concentration of Zn. The linden leaves from the roadside were characterized by the increase in As, Cu, Fe, Zn, and Cr and sharp decrease in the Mn and Sr concentrations. The analysis of soil water extracts showed a slight decrease of pH and low content of Ca, Mg, K, and Na for the distant sites. The phytochelatin test of linden leaves was weakly effective as well as asymmetry degree study of leaf lamina. The main differences were observed in the damage symptoms of leaves (chlorosis and necrosis) and the content of pigments (chlorophyll and carotenoids). The biochemical and ecological assessment of soils and trees showed relatively satisfactory ecological state of the investigated area in Moscow. The data obtained shows the weak local impact of the application of de-icing salts and automobile emissions.

<p>The comparative assessment of the levels of content and migration parameters of biologically active chemical elements in the biogeochemical food chains of the main localities of the Urov  endemic disease in the Eastern Transbaikalia: rocks-soils-plants-animal hair, milk was conducted. The differentiated polyelement microelementosis with an excess of Sr [1], Mn, Cr, Ni, in some cases – P, Ba, As, Zn  and deficiency of Se, J, Cu, and Mo is typical in Urov biogeochemical provinces of Eastern Transbaikalia against the background territories. Soil landscapes are not much different in content of selenium, but its migration in plants was reduced in places of spread of Urov disease. Parameters of migration of chemical elements in the soil-plant complex reflected on their content in wheat, hair cover of animals and milk cows. The sources of this imbalance are soil-forming rocks, specific conditions of soil formation (accumulation of organic matter in freezing soils of narrow valleys with a high degree of moisture and low flow, and selective concentration by plants). For floodplain soils with a high level of organic matter is characterized by a high content of micromycetes of the genus Fusarium as their species composition and abundance. The data obtained are consistent with the results of research by Chinese scientists on the assessment of the chemical elemental composition of hair in healthy children and with Urov Kashin-Beck pathology [2] and considered as risk factors in the genesis of this endemic disease.</p><div>Funding</div><div>This study was supported by the Russian Foundation for Basic Research, project No. 19-05-00054</div><div> </div><p>References</p><ol><li>Ermakov V.V., U. A. Gulyaeva, S. F. Tyutikov, T. G. Kuz’mina, and V. A. Safonov. Biogeochemistry of Calcium and Strontium in the Landscapes of Eastern Transbaikalia. Geochemistry International, 2017, 55 (12). P. 1105–1117. https://link.springer.com/article/10.1134%2FS0016702917090026</li> <li>Wang X., Ning Y., Zhang P., Li C., Zhou R., Guo X. Hair multi-bioelement profile of Kashin-Beck disease in the endemic regions of China. J Trace Elem Med Biol., 2019. 54 (July 2019). P. 79-97. https://rareomics.healx.io/disease/kashin-beck-disease.</li> </ol>