The unified geometrical interpretation of the linear character of the Zeno-line (unit compressibility line Z = 1) and the rectilinear diameter is proposed. We show that recent findings about the properties of the Zeno-line and striking correlation with the rectilinear diameter line as well as other empirical relations can be naturally considered as the consequences of the projective isomorphism between the real molecular fluids and the lattice gas (Ising) model.

The interpretation of the linear character of the observable classic rectilinear diameter law and the linear character of the Zeno-line (unit compressibility line Z=1) on the basis of global isomorphism between Ising model (lattice gas) and simple fluid is proposed. The correct definition of the limiting nontrivial Zeno state is given and its relation to the locus of the critical point is derived within this approach. We show that the liquid-vapor part of the phase diagram of the molecular fluids can be described as the isomorphic image of the phase diagram of the lattice gas. It is shown how the position of the critical points of the fluids of the Lennard-Jones type can be determined based on the scaling symmetry. As a sequence, the explanation of the well-known fact about "global" cubic character of the coexistence curve of the molecular fluids is proposed.

In this paper we apply the global isomorphism approach [V. L. Kulinskii, J. Phys. Chem. B

We consider physical interpretations of non-trivial boundary conditions of self-adjoint extensions for one-dimensional Schrödinger operator of free spinless particle. Despite its model and rather abstract character this question is worth of investigation due to application for one-dimensional nanostructures. The main result is the physical interpretation of peculiar self-adjoint extension with discontinuity of both the probability density and the derivative of the wave function. We show that this case differs very much from other three which were considered before and corresponds to the presence of mass-jump in a sense of works of Ganella et. al.

In this communication we show that the surface tension of the real fluids of the Lennard-Jones type can be obtained from the surface tension of the lattice gas (Ising model) on the basis of the global isomorphism approach developed earlier for the bulk properties.