Evidence is presented to support the conclusion that pore fluid pressures tresses PF during regional metamorphism are generally greater than or equal to the minimum principal compressive stress S3. The resultant very low effective stresses σ lead to significantly increased porosity and permeability, even at moderate to high metamorphic temperatures. Permeabilities between 10−18 and 10−15 m2 and are considered to be common, resulting in rapid fluid migration and the dominance of advective (infiltrative) over diffusive mass transport, even over relatively small distances. In view of the importance of intergranular mass transport to rock deformation during metamorphism, a mobile, high‐pressure fluid will have substantial rheological effects, especially in polyphase rocks. The fluid is capable of influencing the rate of dislocation creep in a number of ways. More importantly, advective mass transport along fluid pressure gradients can give rise to a solution transfer deformation mechanism that competes with conventional pressure solution. The rate of deformation by advective mass transport could be controlled by a number of processes, including dissolution kinetics, advective transport rates, and the rate of crack growth. A specific deformation model, based on advective transport rate control,is developed, which can produce strain at competitive rates but with stress and temperature dependences of unusual form.
Abstract. Evidence from rock microstructures, mass transfer and isotopic exchange indicates that substantial quantities of aqueous fluids are involved in low-and medium-grade regional metamorphism. Similar conclusions are drawn from many retrograde environments, whereas high-grade metamorphic fluids may be melt dominated. The mobile fluids play essential roles in metamorphic reactions, mass transport and deformation processes. These processes are linked by the mechanical consequences of metamorphic fluid pressures (Pr) generally being greater than or equal to the minimum principal compressive stress. Under such conditions metamorphic porosity comprises grain boundary tubules and bubbles together with continuously generated (and healed) microfractures. Deformation results in significant interconnected porosity and hence enhanced permeability. Lithologically and structurally controlled permeability variations may cause effective fluid channelling.Simple Rayleigh-Darcy modelling of a uniformly permeable, crustal slab shows that convective instability of metamorphic fluid is expected at the permeabilities suggested for the high Pf metamorphic conditions. Complex, largescale convective cells operating in overpressured, but capped systems may provide a satisfactory explanation for the large fluid/rock ratios and extensive mass transport demonstrated for many low-and medium-grade metamorphic environments. Such large-scale fluid circulation may have important consequences for heat transfer in and the thermal evolution of metamorphic belts.
Large calcite veins and pods in the Proterozoic Corella Formation of the Mount Isa Inlier provide evidence for kilometre-scale fluid transport during amphibolite facies metamorphism. These 11% to lWm-scale podiform veins and their surrounding alteration zones have similar oxygen and carbon isotopic ratios throughout the 200 x 10-km Mary Kathleen Fold Belt, despite the isotopic heterogeneity of the surrounding wallrocks. The fluids that formed the pods and veins were not in isotopic equilibrium with the immediately adjacent rocks. The pods have S13Cakirc values of -2 to -7%. and 6180ulfilc values of 10.5 to 12.5%. Away from the pods, metadolerite wallrocks have 6180whorc-mck values of 3.5 to 7%., and unaltered banded calc-silicate and marble wallrocks have S"C,,,, of -1.6 to -0.6% and ,5180w,e of 18 to 21%. In the alteration zones adjacent to the pods, the 6l8O values of both metadolerite and calc-silicate rocks approach those of the pods. Large calcite pods hosted entirely in calc-silicates show little difference in isotopic composition from pods hosted entirely in metadolerite. Thus, 100-to 500-m-scale isotopic exchange with the surrounding metadolerites and calc-silicates does not explain the observation that the 6"O values of the pods are intermediate between these two rock types. Pods hosted in felsic metavolcanics and metasiltstones are also isotopically indistinguishable from those hosted in the dominant metadolerites and calc-silicates. These data suggest the veins are the product of infiltration of isotopically homogeneous fluids that were not derived from within the Corella Formation at the presently exposed crustal level, although some of the spread in the data may be due to a relatively small contribution from devolatilization reactions in the calc-silicates, or thermal fluctuations attending deformation and metamorphism. The overall L-shaped trend of the data on plots of 6I3C vs. 6I80 is most consistent with mixing of large volumes of externally derived fluids with small volumes of locally derived fluid produced by devolatilization of calc-silicate rocks. Localization of the vein systems in dilatant sites around metadolerite/calc-silicate boundaries indicates a strong structural control on fluid flow, and the stable isotope data suggest fluid migration must have occurred at scales greater than at least 1 km. The ultimate source for the external fluid is uncertain, but is probably fluid released from crystallizing melts derived from the lower crust or upper mantle. Intrusion of magmas below the exposed crustal level would also explain the high geothermal gradient calculated for the regional metamorphism.
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