Context. Circumstellar discs around massive stars could mediate the accretion onto the star from the infalling envelope, and could minimize the effects of radiation pressure. Despite such a crucial role, only a few convincing candidates have been provided for discs around deeply embedded O-type (proto)stars. Aims. In order to establish whether disc-mediated accretion is the formation mechanism for the most massive stars, we have searched for circumstellar, rotating discs around a limited sample of six luminous (>10 5 L ) young stellar objects. These objects were selected on the basis of their IR and radio properties in order to maximize the likelihood of association with disc+jet systems. Methods. We used ALMA with ∼0 . 2 resolution to observe a large number of molecular lines typical of hot molecular cores. In this paper we limit our analysis to two disc tracers (methyl cyanide, CH 3 CN, and its isotopologue, 13 CH 3 CN), and an outflow tracer (silicon monoxide, SiO). Results. We reveal many cores, although their number depends dramatically on the target. We focus on the cores that present prominent molecular line emission. In six of these a velocity gradient is seen across the core, three of which show evidence of Keplerian-like rotation. The SiO data reveal clear but poorly collimated bipolar outflow signatures towards two objects only. This can be explained if real jets are rare (perhaps short-lived) in very massive objects and/or if stellar multiplicity significantly affects the outflow structure. For all cores with velocity gradients, the velocity field is analysed through position-velocity plots to establish whether the gas is undergoing rotation with rot ∝ R −α , as expected for Keplerian-like discs. Conclusions. Our results suggest that in three objects we are observing rotation in circumstellar discs, with three more tentative cases, and one core where no evidence for rotation is found. In all cases but one, we find that the gas mass is less than the mass of any embedded O-type star, consistent with the (putative) discs undergoing Keplerian-like rotation. With the caveat of low number statistics, we conclude that the disc detection rate could be sensitive to the evolutionary stage of the young stellar object. In young, deeply embedded sources, the evidence for discs could be weak because of confusion with the surrounding envelope, while in the most evolved sources the molecular component of the disc could have already been dispersed. Only in those objects that are at an intermediate stage of the evolution would the molecular disc be sufficiently prominent and relatively less embedded to be detectable by mm/submm observations.

As part of our effort to search for circumstellar disks around high-mass stellar objects, we observed the well-known core G31.41+0.31 with ALMA at 1.4 mm with an angular resolution of ∼0 ′′ .22 (∼1700 au). The dust continuum emission has been resolved into two cores namely Main and NE. The Main core, which has the stronger emission and is the more chemically rich, has a diameter of ∼5300 au, and is associated with two free-free continuum sources. The Main core looks featureless and homogeneous in dust continuum emission and does not present any hint of fragmentation. Each transition of CH3CN and CH3OCHO, both ground and vibrationally excited, as well as those of CH3CN isotopologues, shows a clear velocity gradient along the NE-SW direction, with velocity linearly increasing with distance from the center, consistent with solid-body rotation. However, when comparing the velocity field of transitions with different upper level energies, the rotation velocity increases with increasing energy of the transition, which suggests that the rotation speeds up towards the center. Spectral lines towards the dust continuum peak show an inverse P-Cygni profile that supports the existence of infall in the core. The infall velocity increases with the energy of the transition suggesting that the infall is accelerating towards the center of the core, consistent with gravitational collapse. Despite the monolithic appearance of the Main core, the presence of red-shifted absorption, the existence of two embedded free-free sources at the center, and the rotational spin-up are consistent with an unstable core undergoing fragmentation with infall and differential rotation due to conservation of angular momentum. Therefore, the most likely explanation for the monolithic morphology is that the large opacity of the dust emission prevents the detection of any inhomogeneity in the core.

Context. In the study of high-mass star formation, hot cores are empirically defined stages where chemically rich emission is detected toward a massive YSO. It is unknown whether the physical origin of this emission is a disk, inner envelope, or outflow cavity wall and whether the hot core stage is common to all massive stars. Aims. We investigate the chemical make up of several hot molecular cores to determine physical and chemical structure. We use high spectral and spatial resolution sub-millimeter observations to determine how this stage fits into the formation sequence of a high mass star. Methods. The sub-millimeter interferometer ALMA (Atacama Large Millimeter Array) was used to observe the G35.20-0.74N and G35.03+0.35 hot cores at 350 GHz in Cycle 0. We analyzed spectra and maps from four continuum peaks (A, B1, B2 and B3) in G35.20-0.74N, separated by 1000-2000 AU, and one continuum peak in G35.03+0.35. We made all possible line identifications across 8 GHz of spectral windows of molecular emission lines down to a 3σ line flux of 0.5 K and determined column densities and temperatures for as many as 35 species assuming local thermodynamic equilibrium (LTE). Results. In comparing the spectra of the four continuum peaks, we find each has a distinct chemical composition expressed in over 400 different transitions. In G35.20, B1 and B2 contain oxygen-and sulfur-bearing organic and inorganic species but few nitrogenbearing species whereas A and B3 are strong sources of O-, S-, and N-bearing organic and inorganic species (especially those with the CN-bond). Column densities of vibrationally excited states are observed to be equal to or greater than the ground state for a number of species. Deuterated methyl cyanide is clearly detected in A and B3 with D/H ratios of 8 and 13%, respectively, but is much weaker at B1 and undetected at B2. No deuterated species are detected in G35.03, but similar molecular abundances to G35.20 were found in other species. We also find co-spatial emission of isocyanic acid (HNCO) and formamide (NH 2 CHO) in both sources indicating a strong chemical link between the two species. Conclusions. The chemical segregation between N-bearing organic species and others in G35.20 suggests the presence of multiple protostars, surrounded by a disk or torus.