Many recent investigations have confirmed the presence of surface barriers in a variety of zeolites. These surface barriers can have a significant effect on the overall rates of mass transfer and have the potential to significantly reduce the effectiveness of zeolites in industrial applications. In this study, the strength of the surface barrier was manipulated in a well-defined way and correlated with the rate of isobutane uptake. Silicalite-1 crystals were synthesized and were surface treated with trimethyl-, triethyland tripropylchlorosilanes. It was hypothesized that with the increasing size of the alkyl group the pore windows would be increasingly blocked, thereby effectively decreasing the pore size and increasing the surface barriers. The rates of adsorption and desorption of isobutane in untreated and treated samples were monitored by infrared microscopy. For differential pressure steps, adsorption and desorption responses were mirror images of one another. For large pressure steps, the rate of adsorption was much higher than that of desorption, indicating a significant variation of intracrystalline diffusivity with loading. The adsorption/desorption curves were analyzed considering (1) the presence of only intracrystalline diffusion and (2) surface barrier followed by intracrystalline diffusion. The measured rates of adsorption/desorption were significantly lower for the surface treated samples when compared with those for the untreated samples. Moreover, the strength of the surface resistance increased with the size of the alkyl group in chlorosilanes used for surface treatment.

The persistence of resistance: In the zeolite silicalite‐1, the influence of transport barrier on the surface and between crystal segments, are negligibly small in comparison to the transport resistance of the intracrystalline pore system. Diffusion experiments are conducted with these zeolite crystals and intracrystalline diffusion coefficients of guest molecules determined.

Mesostructured silica fibers constitute a class of highly ordered solidswhose reciprocal space consists of well‐defined extended ring structures (see Figure). Their X‐ray diffraction spots cannot be described by the Bragg equation: As described here, they exhibit unusual intensity differences between symmetry‐related spots and local minima arising from the circular fiber architecture (see also cover).

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Single-crystal segments of tetra-n-propylammonium-templated Silicalite-1 and ZSM-5 were prepared by postsynthetic treatment of twinned MFI prisms. Microwave irradiation of the parent crystallites in alkaline solution containing hydrogen peroxide, followed by ultrasound treatment, led to disintegration of the zeolite prisms. The resulting wedge-shaped crystal segments proved to be single crystals of excellent crystallinity as shown by optical and X-ray investigations. The hydroxyl ions, compensating the positive charges of the tetrapropylammonium cations, were located by single-crystal structure refinement in template-containing Silicalite-1 and ZSM-5 but absent from the calcined samples.